Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications

Graphitic carbon nitride (g-C3N4) has been considered as a metal-free, cost-effective, eco-friendly and efficient catalyst for various photoelectrochemical applications. However, compared to conventional metal-based photocatalysts, its photocatalytic activity is still low because of the low mobility...

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Main Authors: Zhou, L., Zhang, H., Guo, X., Sun, Hongqi, Liu, Shaomin, Tade, Moses, Wang, Shaobin
Format: Journal Article
Published: Academic Press 2017
Online Access:http://purl.org/au-research/grants/arc/DP150103026
http://hdl.handle.net/20.500.11937/51028
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author Zhou, L.
Zhang, H.
Guo, X.
Sun, Hongqi
Liu, Shaomin
Tade, Moses
Wang, Shaobin
author_facet Zhou, L.
Zhang, H.
Guo, X.
Sun, Hongqi
Liu, Shaomin
Tade, Moses
Wang, Shaobin
author_sort Zhou, L.
building Curtin Institutional Repository
collection Online Access
description Graphitic carbon nitride (g-C3N4) has been considered as a metal-free, cost-effective, eco-friendly and efficient catalyst for various photoelectrochemical applications. However, compared to conventional metal-based photocatalysts, its photocatalytic activity is still low because of the low mobility of carriers restricted by the polymer nature. Herein, a series of hybrids of g-C3N4 (GCN) and nanodiamonds (NDs) were synthesized using a solvothermal method. The photoelectrochemical performance and photocatalytic efficiency of the GCN/NDs were investigated by means of the generation of photocurrent and photodegradation of methylene blue (MB) solutions under UV–visible light irradiations. In this study, the sample of GCN/ND-33% derived from 0.1 g GCN and 0.05 g NDs displayed the highest photocatalytic activity and the strongest photocurrent density. The mechanism of enhanced photoelectrochemical and photocatalytic performances was also discussed.
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institution Curtin University Malaysia
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publishDate 2017
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spelling curtin-20.500.11937-510282022-10-26T06:28:56Z Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications Zhou, L. Zhang, H. Guo, X. Sun, Hongqi Liu, Shaomin Tade, Moses Wang, Shaobin Graphitic carbon nitride (g-C3N4) has been considered as a metal-free, cost-effective, eco-friendly and efficient catalyst for various photoelectrochemical applications. However, compared to conventional metal-based photocatalysts, its photocatalytic activity is still low because of the low mobility of carriers restricted by the polymer nature. Herein, a series of hybrids of g-C3N4 (GCN) and nanodiamonds (NDs) were synthesized using a solvothermal method. The photoelectrochemical performance and photocatalytic efficiency of the GCN/NDs were investigated by means of the generation of photocurrent and photodegradation of methylene blue (MB) solutions under UV–visible light irradiations. In this study, the sample of GCN/ND-33% derived from 0.1 g GCN and 0.05 g NDs displayed the highest photocatalytic activity and the strongest photocurrent density. The mechanism of enhanced photoelectrochemical and photocatalytic performances was also discussed. 2017 Journal Article http://hdl.handle.net/20.500.11937/51028 10.1016/j.jcis.2017.01.038 http://purl.org/au-research/grants/arc/DP150103026 Academic Press restricted
spellingShingle Zhou, L.
Zhang, H.
Guo, X.
Sun, Hongqi
Liu, Shaomin
Tade, Moses
Wang, Shaobin
Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title_full Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title_fullStr Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title_full_unstemmed Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title_short Metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
title_sort metal-free hybrids of graphitic carbon nitride and nanodiamonds for photoelectrochemical and photocatalytic applications
url http://purl.org/au-research/grants/arc/DP150103026
http://hdl.handle.net/20.500.11937/51028