Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour

Ag nanoparticles were photodeposited on the {101} crystal facets of the TiO2 anatase nanoplates. This was achieved with the photoreduction of AgNO3 in methanol solution in which TiO2 anatase nanoplates were suspended while UVA irradiation was performed. The size range of the photodeposited silver na...

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Main Authors: Sofianou, Maria, Boukos, N., Vaimakis, T., Trapalis, C.
Format: Journal Article
Published: Elsevier BV 2014
Online Access:http://hdl.handle.net/20.500.11937/51024
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author Sofianou, Maria
Boukos, N.
Vaimakis, T.
Trapalis, C.
author_facet Sofianou, Maria
Boukos, N.
Vaimakis, T.
Trapalis, C.
author_sort Sofianou, Maria
building Curtin Institutional Repository
collection Online Access
description Ag nanoparticles were photodeposited on the {101} crystal facets of the TiO2 anatase nanoplates. This was achieved with the photoreduction of AgNO3 in methanol solution in which TiO2 anatase nanoplates were suspended while UVA irradiation was performed. The size range of the photodeposited silver nanoparticles was between 5 and 20nm. The manipulation of their size was achieved by controlling the UVA light irradiation period of time whereas the formation on the specific facet of the TiO2 anatase nanocrystal was managed by using methanol as a hole scavenger. The silver ions (Ag+) were photoreduced by the electrons that were photogenerated due to the TiO2 anatase nanoplates irradiation with UVA light. The photocatalytic activity of the nanocomposites was examined in NO oxidation, showing a higher photocatalytic activity and photonic efficiency in comparison to the pure TiO2 anatase nanoplates. © 2014 Elsevier B.V.
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spelling curtin-20.500.11937-510242017-09-13T15:34:50Z Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour Sofianou, Maria Boukos, N. Vaimakis, T. Trapalis, C. Ag nanoparticles were photodeposited on the {101} crystal facets of the TiO2 anatase nanoplates. This was achieved with the photoreduction of AgNO3 in methanol solution in which TiO2 anatase nanoplates were suspended while UVA irradiation was performed. The size range of the photodeposited silver nanoparticles was between 5 and 20nm. The manipulation of their size was achieved by controlling the UVA light irradiation period of time whereas the formation on the specific facet of the TiO2 anatase nanocrystal was managed by using methanol as a hole scavenger. The silver ions (Ag+) were photoreduced by the electrons that were photogenerated due to the TiO2 anatase nanoplates irradiation with UVA light. The photocatalytic activity of the nanocomposites was examined in NO oxidation, showing a higher photocatalytic activity and photonic efficiency in comparison to the pure TiO2 anatase nanoplates. © 2014 Elsevier B.V. 2014 Journal Article http://hdl.handle.net/20.500.11937/51024 10.1016/j.apcatb.2014.02.030 Elsevier BV restricted
spellingShingle Sofianou, Maria
Boukos, N.
Vaimakis, T.
Trapalis, C.
Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title_full Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title_fullStr Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title_full_unstemmed Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title_short Decoration of TiO2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
title_sort decoration of tio2 anatase nanoplates with silver nanoparticles on the {101} crystal facets and their photocatalytic behaviour
url http://hdl.handle.net/20.500.11937/51024