Sulfurized metal borohydrides
© 2016 The Royal Society of Chemistry.The reactions between metal borohydrides and elemental sulfur are investigated in situ during thermal treatment and are found to be highly exothermic (up to 700 J g-1). These reactions are exceptionally rapid, occurring below 200°C, also resulting in the sudden...
| Main Authors: | , , , , |
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| Format: | Journal Article |
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R S C Publications
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/50809 |
| _version_ | 1848758541168410624 |
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| author | Paskevicius, Mark Richter, B. Polanski, M. Thompson, S. Jensen, T. |
| author_facet | Paskevicius, Mark Richter, B. Polanski, M. Thompson, S. Jensen, T. |
| author_sort | Paskevicius, Mark |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2016 The Royal Society of Chemistry.The reactions between metal borohydrides and elemental sulfur are investigated in situ during thermal treatment and are found to be highly exothermic (up to 700 J g-1). These reactions are exceptionally rapid, occurring below 200°C, also resulting in the sudden release of substantial quantities of hydrogen gas. For NaBH4 this hydrogen release is pure, with no detectable levels of H2S or B2H6. The reaction results in the formation of an array of metal-boron-sulfur compounds. These MBH4-S compounds are interesting for possible uses in high energy applications (fuels or explosives), hydrogen generation, and metal-boron-sulfur precursors. |
| first_indexed | 2025-11-14T09:45:37Z |
| format | Journal Article |
| id | curtin-20.500.11937-50809 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:45:37Z |
| publishDate | 2015 |
| publisher | R S C Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-508092017-09-13T15:34:51Z Sulfurized metal borohydrides Paskevicius, Mark Richter, B. Polanski, M. Thompson, S. Jensen, T. © 2016 The Royal Society of Chemistry.The reactions between metal borohydrides and elemental sulfur are investigated in situ during thermal treatment and are found to be highly exothermic (up to 700 J g-1). These reactions are exceptionally rapid, occurring below 200°C, also resulting in the sudden release of substantial quantities of hydrogen gas. For NaBH4 this hydrogen release is pure, with no detectable levels of H2S or B2H6. The reaction results in the formation of an array of metal-boron-sulfur compounds. These MBH4-S compounds are interesting for possible uses in high energy applications (fuels or explosives), hydrogen generation, and metal-boron-sulfur precursors. 2015 Journal Article http://hdl.handle.net/20.500.11937/50809 10.1039/c5dt04304b R S C Publications restricted |
| spellingShingle | Paskevicius, Mark Richter, B. Polanski, M. Thompson, S. Jensen, T. Sulfurized metal borohydrides |
| title | Sulfurized metal borohydrides |
| title_full | Sulfurized metal borohydrides |
| title_fullStr | Sulfurized metal borohydrides |
| title_full_unstemmed | Sulfurized metal borohydrides |
| title_short | Sulfurized metal borohydrides |
| title_sort | sulfurized metal borohydrides |
| url | http://hdl.handle.net/20.500.11937/50809 |