From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors

We herein report the synthesis of heteroatoms doped, high surface area microporous activated carbons (AC) by utilisation of Coca Cola® as a potential source of waste biomass, for applications as CO2 adsorbent and electrodes of supercapacitors. N, S dual doped carbon spheres are firstly obtained by h...

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Main Authors: Boyjoo, Y., Cheng, Y., Zhong, H., Tian, H., Pan, J., Pareek, Vishnu, Jiang, S., Lamonier, J., Jaroniec, M., Liu, J.
Format: Journal Article
Published: Pergamon 2017
Online Access:http://hdl.handle.net/20.500.11937/50775
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author Boyjoo, Y.
Cheng, Y.
Zhong, H.
Tian, H.
Pan, J.
Pareek, Vishnu
Jiang, S.
Lamonier, J.
Jaroniec, M.
Liu, J.
author_facet Boyjoo, Y.
Cheng, Y.
Zhong, H.
Tian, H.
Pan, J.
Pareek, Vishnu
Jiang, S.
Lamonier, J.
Jaroniec, M.
Liu, J.
author_sort Boyjoo, Y.
building Curtin Institutional Repository
collection Online Access
description We herein report the synthesis of heteroatoms doped, high surface area microporous activated carbons (AC) by utilisation of Coca Cola® as a potential source of waste biomass, for applications as CO2 adsorbent and electrodes of supercapacitors. N, S dual doped carbon spheres are firstly obtained by hydrothermal treatment of Coca Cola® and then thermally activated by either KOH or ZnCl2. The resulting KOH activated carbon material (CMC-3) exhibits extremely high adsorption capability for CO2 with 5.22 mmol g-1 at 25 °C and 1 atm, one of the highest values ever recorded for a carbonaceous material. On the other hand, ZnCl2 activated carbon material (CMC-2) performs excellently as an electrode for supercapacitor, exhibiting very high specific capacitance of 352.7 F g-1 at a current density of 1 A g-1 in 6 M KOH electrolyte, which again is one of the highest values recorded for a biomass derived AC. Coca Cola® has high content in carbon as sugars, provides in-situ doping of O, N and S and has constant composition, as opposed to other conventional biomass materials, making it an attractive and cheap alternative for synthesis of high performance AC for environmental and energy storage purposes.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:45:30Z
publishDate 2017
publisher Pergamon
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spelling curtin-20.500.11937-507752017-09-13T15:40:42Z From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors Boyjoo, Y. Cheng, Y. Zhong, H. Tian, H. Pan, J. Pareek, Vishnu Jiang, S. Lamonier, J. Jaroniec, M. Liu, J. We herein report the synthesis of heteroatoms doped, high surface area microporous activated carbons (AC) by utilisation of Coca Cola® as a potential source of waste biomass, for applications as CO2 adsorbent and electrodes of supercapacitors. N, S dual doped carbon spheres are firstly obtained by hydrothermal treatment of Coca Cola® and then thermally activated by either KOH or ZnCl2. The resulting KOH activated carbon material (CMC-3) exhibits extremely high adsorption capability for CO2 with 5.22 mmol g-1 at 25 °C and 1 atm, one of the highest values ever recorded for a carbonaceous material. On the other hand, ZnCl2 activated carbon material (CMC-2) performs excellently as an electrode for supercapacitor, exhibiting very high specific capacitance of 352.7 F g-1 at a current density of 1 A g-1 in 6 M KOH electrolyte, which again is one of the highest values recorded for a biomass derived AC. Coca Cola® has high content in carbon as sugars, provides in-situ doping of O, N and S and has constant composition, as opposed to other conventional biomass materials, making it an attractive and cheap alternative for synthesis of high performance AC for environmental and energy storage purposes. 2017 Journal Article http://hdl.handle.net/20.500.11937/50775 10.1016/j.carbon.2017.02.030 Pergamon restricted
spellingShingle Boyjoo, Y.
Cheng, Y.
Zhong, H.
Tian, H.
Pan, J.
Pareek, Vishnu
Jiang, S.
Lamonier, J.
Jaroniec, M.
Liu, J.
From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title_full From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title_fullStr From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title_full_unstemmed From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title_short From waste Coca Cola® to activated carbons with impressive capabilities for CO2 adsorption and supercapacitors
title_sort from waste coca cola® to activated carbons with impressive capabilities for co2 adsorption and supercapacitors
url http://hdl.handle.net/20.500.11937/50775