The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry

Over the past century, numerous aspects of the reaction between urea and hypobromite have been exploited to quantify urea in clinical and industrial process samples. A review of these analytical approaches provides an interesting illustration of changes in a chemical system that indicate a reaction...

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Main Authors: Francis, P., Lim, K., Lewis, Simon
Format: Journal Article
Published: The Chemical Educator 2005
Online Access:http://chemeducator.org/bibs/0010006/1060419pf.htm
http://hdl.handle.net/20.500.11937/5058
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author Francis, P.
Lim, K.
Lewis, Simon
author_facet Francis, P.
Lim, K.
Lewis, Simon
author_sort Francis, P.
building Curtin Institutional Repository
collection Online Access
description Over the past century, numerous aspects of the reaction between urea and hypobromite have been exploited to quantify urea in clinical and industrial process samples. A review of these analytical approaches provides an interesting illustration of changes in a chemical system that indicate a reaction has occurred-the production of a gas, a color change, the release of heat, and the emission of light-and a variety of instruments that were developed to measure these changes and quantify a reacting species. In this paper we describe how we have used this material in a tutorial class for first-year undergraduate (freshman) students and a follow-up assignment, which we have included in the supporting material. In addition to the concepts exemplified by the above phenomena, we discuss the reaction pathway, which includes examples of ion and atom transfer. These are often overlooked in favor of electron transfer in the teaching of redox chemistry.
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spelling curtin-20.500.11937-50582017-02-28T01:29:29Z The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry Francis, P. Lim, K. Lewis, Simon Over the past century, numerous aspects of the reaction between urea and hypobromite have been exploited to quantify urea in clinical and industrial process samples. A review of these analytical approaches provides an interesting illustration of changes in a chemical system that indicate a reaction has occurred-the production of a gas, a color change, the release of heat, and the emission of light-and a variety of instruments that were developed to measure these changes and quantify a reacting species. In this paper we describe how we have used this material in a tutorial class for first-year undergraduate (freshman) students and a follow-up assignment, which we have included in the supporting material. In addition to the concepts exemplified by the above phenomena, we discuss the reaction pathway, which includes examples of ion and atom transfer. These are often overlooked in favor of electron transfer in the teaching of redox chemistry. 2005 Journal Article http://hdl.handle.net/20.500.11937/5058 http://chemeducator.org/bibs/0010006/1060419pf.htm The Chemical Educator restricted
spellingShingle Francis, P.
Lim, K.
Lewis, Simon
The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title_full The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title_fullStr The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title_full_unstemmed The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title_short The Determination of Urea with Hypobromite: A Theme for the Discussion of Numerous Fundamental Concepts in Chemistry
title_sort determination of urea with hypobromite: a theme for the discussion of numerous fundamental concepts in chemistry
url http://chemeducator.org/bibs/0010006/1060419pf.htm
http://hdl.handle.net/20.500.11937/5058