Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes
1,1-Dimethylcycloprop[e]azulene and 1,1-dimethylcyclo-prop[f]azulene derivatives were prepared through a short syn-thesis from thiophene-1,1-dioxides using a Houk-Leaver azu-lene synthesis. The strain caused by the fusion of thecyclopropane ring had no effect on electrophilic aromatic sub-stitution...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
2016
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| Online Access: | http://hdl.handle.net/20.500.11937/50398 |
| _version_ | 1848758465941471232 |
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| author | Payne, Alan Skelton, B. White, A. Wege, D. |
| author_facet | Payne, Alan Skelton, B. White, A. Wege, D. |
| author_sort | Payne, Alan |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | 1,1-Dimethylcycloprop[e]azulene and 1,1-dimethylcyclo-prop[f]azulene derivatives were prepared through a short syn-thesis from thiophene-1,1-dioxides using a Houk-Leaver azu-lene synthesis. The strain caused by the fusion of thecyclopropane ring had no effect on electrophilic aromatic sub-stitution reactions. X-ray structures of these compoundsshowed that cycloprop[e] azulenes have no or very small straininduced bond localisation, whereas cycloprop[f]azulene showssome minor localisation. |
| first_indexed | 2025-11-14T09:44:26Z |
| format | Journal Article |
| id | curtin-20.500.11937-50398 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:44:26Z |
| publishDate | 2016 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-503982017-09-13T15:34:03Z Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes Payne, Alan Skelton, B. White, A. Wege, D. 1,1-Dimethylcycloprop[e]azulene and 1,1-dimethylcyclo-prop[f]azulene derivatives were prepared through a short syn-thesis from thiophene-1,1-dioxides using a Houk-Leaver azu-lene synthesis. The strain caused by the fusion of thecyclopropane ring had no effect on electrophilic aromatic sub-stitution reactions. X-ray structures of these compoundsshowed that cycloprop[e] azulenes have no or very small straininduced bond localisation, whereas cycloprop[f]azulene showssome minor localisation. 2016 Journal Article http://hdl.handle.net/20.500.11937/50398 10.1002/slct.201601168 restricted |
| spellingShingle | Payne, Alan Skelton, B. White, A. Wege, D. Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title_full | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title_fullStr | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title_full_unstemmed | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title_short | Synthesis, Chemistry and Structure of Some 1,1-Dimethylcyclopropazulenes |
| title_sort | synthesis, chemistry and structure of some 1,1-dimethylcyclopropazulenes |
| url | http://hdl.handle.net/20.500.11937/50398 |