Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets

TiO2 anatase nanoplates, hollow microspheres and microcrystals with exposed {001} crystal facets were fabricated via a solvothermal- hydrothermal method at 180 °C for 24 hours using titanium isopropoxide or titanium tetrafluoride as a titanium precursor, ethanol or distilled water as a solvent and l...

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Main Authors: Sofianos, Veronica, Vaimakis, T., Trapalis, C.
Format: Conference Paper
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/50232
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author Sofianos, Veronica
Vaimakis, T.
Trapalis, C.
author_facet Sofianos, Veronica
Vaimakis, T.
Trapalis, C.
author_sort Sofianos, Veronica
building Curtin Institutional Repository
collection Online Access
description TiO2 anatase nanoplates, hollow microspheres and microcrystals with exposed {001} crystal facets were fabricated via a solvothermal- hydrothermal method at 180 °C for 24 hours using titanium isopropoxide or titanium tetrafluoride as a titanium precursor, ethanol or distilled water as a solvent and lastly hydrofluoric acid as the enhancer for the formation of the TiO2 anatase {001} crystal facets. All samples were calcined at 600 °C in order to remove the fluoride atoms adsorbed on the photocatalysts surface. This paper presents the influence of different TiO2 anatase structures in their photocatalytic activity. The photocatalytic evaluation of all TiO2 anatase structures with exposed {001} crystal facets was obtained by oxidizing the NO gas to NO2 and NO3- and then calculating their photonic efficiency. Commercial TiO 2 photocatalyst P25 by Evonik Degussa was used as a reference. The TiO2 anatase nanoplates were the structure that exhibited the best photocatalytic activity of all TiO2 anatase structures, including the used reference P25 by Evonik Degussa.
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spelling curtin-20.500.11937-502322017-09-13T15:41:42Z Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets Sofianos, Veronica Vaimakis, T. Trapalis, C. TiO2 anatase nanoplates, hollow microspheres and microcrystals with exposed {001} crystal facets were fabricated via a solvothermal- hydrothermal method at 180 °C for 24 hours using titanium isopropoxide or titanium tetrafluoride as a titanium precursor, ethanol or distilled water as a solvent and lastly hydrofluoric acid as the enhancer for the formation of the TiO2 anatase {001} crystal facets. All samples were calcined at 600 °C in order to remove the fluoride atoms adsorbed on the photocatalysts surface. This paper presents the influence of different TiO2 anatase structures in their photocatalytic activity. The photocatalytic evaluation of all TiO2 anatase structures with exposed {001} crystal facets was obtained by oxidizing the NO gas to NO2 and NO3- and then calculating their photonic efficiency. Commercial TiO 2 photocatalyst P25 by Evonik Degussa was used as a reference. The TiO2 anatase nanoplates were the structure that exhibited the best photocatalytic activity of all TiO2 anatase structures, including the used reference P25 by Evonik Degussa. 2013 Conference Paper http://hdl.handle.net/20.500.11937/50232 10.1166/nnl.2013.1556 restricted
spellingShingle Sofianos, Veronica
Vaimakis, T.
Trapalis, C.
Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title_full Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title_fullStr Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title_full_unstemmed Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title_short Study of the photocatalytic activity of anatase TiO2 nano-microstructures with exposed {001} facets
title_sort study of the photocatalytic activity of anatase tio2 nano-microstructures with exposed {001} facets
url http://hdl.handle.net/20.500.11937/50232