New tetrazole-based Cu(I) homo- and heteroleptic complexes with various P^P ligands: synthesis,characterization, redox and photophysical properties.

New tetrazole-based Cu(I) homo- and heteroleptic complexes with various P^P ligands: synthesis,characterization, redox and photophysical properties.

Four Cu(I) complexes with general formulas [Cu(N^N)2][BF4] and [(P^P)Cu(N^N)][BF4] were prepared,where N^N stands for 2-(2-tert-butyl-2H-tetrazol-5-yl)pyridine and P^P is a chelating diphosphine,namely bis-(diphenylphosphino)methane (dppm), bis-(diphenylphosphino)ethane (dppe) or bis[2-(diphenylphos...

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Bibliographic Details
Main Authors: Femoni, C., Muzzioli, S., Palazzi, A., Stagni, S., Zacchini, S., Monti, F., Accorsi, G., Bolognesi, M., Armaroli, N., Massi, Massimiliano, Valenti, G., Marcaccio, M.
Format: Journal Article
Published: The Royal Society of Chemistry 2013
Subjects:
redox
heteroleptic
Cu(I)
P^P ligands
photophysical
tetrazole-based
homoleptic
synthesis
Online Access:http://hdl.handle.net/20.500.11937/49594

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