Post-synthetic cation exchange in the robust metal-organic framework MIL-101(Cr)

Post-synthetic cation exchange in the robust metal-organic framework MIL-101(Cr)

In this work an unambiguous proof of post-synthetic solvent-assisted cation exchange in the robust metal-organic framework MIL-101(Cr) is reported. Such substitution can alter directly the secondary building unit, which often defines the properties of the material.

Bibliographic Details
Main Authors: Szilagyi, Petra, Serra-Crespo, P., Dugulan, I., Gascon, J., Geerlings, H., Dam, B.
Format: Journal Article
Published: The Royal Society of Chemistry 2013
Subjects:
Hydrogen storage
MOFS
Acid
NH2-MIL-101(AL)
Adsorption
Performance
Online Access:http://hdl.handle.net/20.500.11937/49467
Description
Summary:In this work an unambiguous proof of post-synthetic solvent-assisted cation exchange in the robust metal-organic framework MIL-101(Cr) is reported. Such substitution can alter directly the secondary building unit, which often defines the properties of the material.

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