Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels

Hydrocarbon fuels are the most important sources of energy in modern society because of their natural abundance, stability, and high energy density. However, the emissions of carbon dioxide from them and the associated global warming effect impose worldwide pressure on the use of sustainable solar e...

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Main Authors: Sun, Hongqi, Wang, Shaobin
Other Authors: Hongwei Wu
Format: Conference Paper
Published: American Chemical Society 2014
Online Access:http://purl.org/au-research/grants/arc/DP130101319
http://hdl.handle.net/20.500.11937/49368
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author Sun, Hongqi
Wang, Shaobin
author2 Hongwei Wu
author_facet Hongwei Wu
Sun, Hongqi
Wang, Shaobin
author_sort Sun, Hongqi
building Curtin Institutional Repository
collection Online Access
description Hydrocarbon fuels are the most important sources of energy in modern society because of their natural abundance, stability, and high energy density. However, the emissions of carbon dioxide from them and the associated global warming effect impose worldwide pressure on the use of sustainable solar energy and carbon dioxide transformation and sequestration. Photocatalytic conversion of CO2 to fuels using semiconductors is proposed as an effective solution. Morerecently, nanocarbons, such as carbon nanotube, graphene oxide, and graphene, possessing high thermal conductivity, high theoretical specific surface area, unique carrier mobility, low-dimensional structure, and sp2-hybridized carbon configuration, have shown promotion to photocatalysis. It has been proven that nanocarbon/semiconductor hybrids can be a competitive materialcompared to traditional metal oxides for CO2 reduction. This review summarizes the recent research advances in the synthesis of nanocarbon hybrid photocatalysts and their applications in photocatalytic reduction of CO2 to hydrocarbons. The roles of nanocarbons in extending light absorption, increasing separation of carriers, band gap engineering, and preferred CO2 adsorptionin manipulating activity/selectivity are discussed. The studies in this topic will facilitate the design of advanced functional materials for energy innovation via solar energy use.
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spelling curtin-20.500.11937-493682023-02-27T07:34:26Z Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels Sun, Hongqi Wang, Shaobin Hongwei Wu Minghou Xu Hydrocarbon fuels are the most important sources of energy in modern society because of their natural abundance, stability, and high energy density. However, the emissions of carbon dioxide from them and the associated global warming effect impose worldwide pressure on the use of sustainable solar energy and carbon dioxide transformation and sequestration. Photocatalytic conversion of CO2 to fuels using semiconductors is proposed as an effective solution. Morerecently, nanocarbons, such as carbon nanotube, graphene oxide, and graphene, possessing high thermal conductivity, high theoretical specific surface area, unique carrier mobility, low-dimensional structure, and sp2-hybridized carbon configuration, have shown promotion to photocatalysis. It has been proven that nanocarbon/semiconductor hybrids can be a competitive materialcompared to traditional metal oxides for CO2 reduction. This review summarizes the recent research advances in the synthesis of nanocarbon hybrid photocatalysts and their applications in photocatalytic reduction of CO2 to hydrocarbons. The roles of nanocarbons in extending light absorption, increasing separation of carriers, band gap engineering, and preferred CO2 adsorptionin manipulating activity/selectivity are discussed. The studies in this topic will facilitate the design of advanced functional materials for energy innovation via solar energy use. 2014 Conference Paper http://hdl.handle.net/20.500.11937/49368 10.1021/ef401426x http://purl.org/au-research/grants/arc/DP130101319 American Chemical Society restricted
spellingShingle Sun, Hongqi
Wang, Shaobin
Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title_full Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title_fullStr Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title_full_unstemmed Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title_short Research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
title_sort research advances in synthesis of nanocarbon-based photocatalysts and their applications for photocatalytic conversion of carbon dioxide to hydrocarbon fuels
url http://purl.org/au-research/grants/arc/DP130101319
http://hdl.handle.net/20.500.11937/49368