MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration
The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leavin...
| Main Authors: | , , , , , , , , |
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| Format: | Journal Article |
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The Royal Society of Chemistry
2013
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/49146 |
| _version_ | 1848758175775326208 |
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| author | Szilagyi, Petra Lutz, M. Gascon, J. Juan-Alcaniz, J. Esch, J. Kapteijn, F. Geerlings, H. Dam, B. Krol, R. |
| author_facet | Szilagyi, Petra Lutz, M. Gascon, J. Juan-Alcaniz, J. Esch, J. Kapteijn, F. Geerlings, H. Dam, B. Krol, R. |
| author_sort | Szilagyi, Petra |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules. |
| first_indexed | 2025-11-14T09:39:49Z |
| format | Journal Article |
| id | curtin-20.500.11937-49146 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:39:49Z |
| publishDate | 2013 |
| publisher | The Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-491462017-09-13T16:09:43Z MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration Szilagyi, Petra Lutz, M. Gascon, J. Juan-Alcaniz, J. Esch, J. Kapteijn, F. Geerlings, H. Dam, B. Krol, R. methane chemistry hydrogen storage fabrication Metal-organice frameworks coordination polymer crystals adsorption functionalization design porosity The effect of strain on core-shell MOFcore@MOFshell particles is discussed and compared with that observed for analogous Janus particles. Whereas Janus particles do not display any effect of strain, the core of fully coated core-shell particles collapsed upon the formation of the outer shell, leaving the core inaccessible for guest adsorption. This suggests that Janus particles might become ideal candidates for gas separation, while core-shell particles could play a key role in sequestration of guest molecules. 2013 Journal Article http://hdl.handle.net/20.500.11937/49146 10.1039/c3ce40653a The Royal Society of Chemistry restricted |
| spellingShingle | methane chemistry hydrogen storage fabrication Metal-organice frameworks coordination polymer crystals adsorption functionalization design porosity Szilagyi, Petra Lutz, M. Gascon, J. Juan-Alcaniz, J. Esch, J. Kapteijn, F. Geerlings, H. Dam, B. Krol, R. MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title | MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title_full | MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title_fullStr | MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title_full_unstemmed | MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title_short | MOF@MOF core–shell vs. Janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| title_sort | mof@mof core–shell vs. janus particles and the effect of strain: potential for guest sorption, separation and sequestration |
| topic | methane chemistry hydrogen storage fabrication Metal-organice frameworks coordination polymer crystals adsorption functionalization design porosity |
| url | http://hdl.handle.net/20.500.11937/49146 |