Effect of pH on calcite growth at constant aCa2+/aCO32- ratio and supersaturation
In situ Atomic Force Microscopy (AFM) was used to study the growth of calcite at a constant supersaturation (O=6.5) and solution stoichiometry (aCa2+/aCO32-=1) in the pH range 7.5-12. The calcite growth rate decreased with increasing pH in the studied range. The results can be successfully explained...
| Main Authors: | Ruiz-Agudo, E., Putnis, Christine, Rodriguez-Navarro, C., Putnis, Andrew |
|---|---|
| Format: | Journal Article |
| Published: |
2011
|
| Online Access: | http://hdl.handle.net/20.500.11937/48040 |
Similar Items
An atomic force microscopy study of the growth of a calcite surface as a function of calcium/total carbonate concentration ratio in solution at constant supersaturation
by: Perdikouri, C., et al.
Published: (2009)
by: Perdikouri, C., et al.
Published: (2009)
Influence of chemical and structural factors on the calcite-calcium oxalate transformation
by: Ruiz-Agudo, E., et al.
Published: (2013)
by: Ruiz-Agudo, E., et al.
Published: (2013)
Boron incorporation into calcite during growth: Implications for the use of boron in carbonates as a pH proxy
by: Ruiz-Agudo, E., et al.
Published: (2012)
by: Ruiz-Agudo, E., et al.
Published: (2012)
Template-assisted crystallization of sulfates onto calcite: Implications for the prevention of salt damage
by: Ruiz-Agudo, E., et al.
Published: (2013)
by: Ruiz-Agudo, E., et al.
Published: (2013)
An atomic force microscopy study of calcite dissolution in saline solutions: The role of magnesium ions
by: Ruiz-Agudo, E., et al.
Published: (2009)
by: Ruiz-Agudo, E., et al.
Published: (2009)
Influence of pH and citrate on the formation of oxalate layers on calcite revealed by in situ nanoscale imaging
by: Burgos-Cara, A., et al.
Published: (2017)
by: Burgos-Cara, A., et al.
Published: (2017)
The influence of pH on barite nucleation and growth
by: Ruiz-Agudo, C., et al.
Published: (2015)
by: Ruiz-Agudo, C., et al.
Published: (2015)
The role of background electrolytes on the kinetics and mechanism of calcite dissolution
by: Ruiz-Agudo, E., et al.
Published: (2010)
by: Ruiz-Agudo, E., et al.
Published: (2010)
Dissolution and carbonation of portlandite [Ca(OH)2] single crystals
by: Ruiz-Agudo, E., et al.
Published: (2013)
by: Ruiz-Agudo, E., et al.
Published: (2013)
Direct observations of mineral-fluid reactions using atomic force microscopy: The specific example of calcite
by: Ruiz-Agudo, E., et al.
Published: (2012)
by: Ruiz-Agudo, E., et al.
Published: (2012)
Direct Nanoscale Imaging Reveals the Growth of Calcite Crystals via Amorphous Nanoparticles
by: Rodriguez-Navarro, C., et al.
Published: (2016)
by: Rodriguez-Navarro, C., et al.
Published: (2016)
Specific effects of background electrolytes on the kinetics of step propagation during calcite growth
by: Ruiz-Agudo, E., et al.
Published: (2011)
by: Ruiz-Agudo, E., et al.
Published: (2011)
Direct observations of the modification of calcite growth morphology by Li+ through selectively stabilizing an energetically unfavourable face
by: Wang, L., et al.
Published: (2011)
by: Wang, L., et al.
Published: (2011)
Posner's cluster revisited: Direct imaging of nucleation and growth of nanoscale calcium phosphate clusters at the calcite-water interface
by: Wang, L., et al.
Published: (2012)
by: Wang, L., et al.
Published: (2012)
Experimental study of the replacement of calcite by calcium sulphates
by: Ruiz-Agudo, E., et al.
Published: (2015)
by: Ruiz-Agudo, E., et al.
Published: (2015)
Kinetics of calcium phosphate nucleation and growth on calcite: Implications for predicting the fate of dissolved phosphate species in alkaline soils
by: Wang, L., et al.
Published: (2012)
by: Wang, L., et al.
Published: (2012)
Mechanism of leached layer formation during chemical weathering of silicate minerals
by: Ruiz-Agudo, E., et al.
Published: (2012)
by: Ruiz-Agudo, E., et al.
Published: (2012)
Sequestration of selenium on calcite surfaces revealed by nanoscale imaging
by: Putnis, Christine, et al.
Published: (2013)
by: Putnis, Christine, et al.
Published: (2013)
Reactions between minerals and aqueous solutions
by: Ruiz-Agudo, E., et al.
Published: (2017)
by: Ruiz-Agudo, E., et al.
Published: (2017)
Interaction between epsomite crystals and organic additives
by: Ruiz-Agudo, E., et al.
Published: (2008)
by: Ruiz-Agudo, E., et al.
Published: (2008)
Selenium incorporation into calcite and its effect on crystal growth: An atomic force microscopy study
by: Renard, F., et al.
Published: (2013)
by: Renard, F., et al.
Published: (2013)
An atomic force microscopy study of the dissolution of calcite in the presence of phosphate ions
by: Klasa, J., et al.
Published: (2013)
by: Klasa, J., et al.
Published: (2013)
Interactions between organophosphonate-bearing solutions and (1014) calcite surfaces: An atomic force microscopy and first-principles molecular dynamics study
by: Ruiz-Agudo, E., et al.
Published: (2010)
by: Ruiz-Agudo, E., et al.
Published: (2010)
Visualizing Organophosphate Precipitation at the Calcite-Water Interface by in Situ Atomic-Force Microscopy
by: Wang, L., et al.
Published: (2016)
by: Wang, L., et al.
Published: (2016)
Interactions of arsenic with calcite surfaces revealed by in situ nanoscale imaging
by: Renard, F., et al.
Published: (2015)
by: Renard, F., et al.
Published: (2015)
AFM study of the epitaxial growth of brushite (CaHPO4� 2H2O) on gypsum cleavage surfaces
by: Pinto, A., et al.
Published: (2010)
by: Pinto, A., et al.
Published: (2010)
The effect of fluid composition on the mechanism of the aragonite to calcite transition
by: Perdikouri, C., et al.
Published: (2008)
by: Perdikouri, C., et al.
Published: (2008)
An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate
by: Vavouraki, A., et al.
Published: (2008)
by: Vavouraki, A., et al.
Published: (2008)
In situ nanoscale observations of the dissolution of {101¯4} dolomite cleavage surfaces
by: Urosevic, M., et al.
Published: (2012)
by: Urosevic, M., et al.
Published: (2012)
Ion-specific effects on the kinetics of mineral dissolution
by: Ruiz-Agudo, E., et al.
Published: (2011)
by: Ruiz-Agudo, E., et al.
Published: (2011)
Macro- to nanoscale study of the effect of aqueous sulphate on calcite growth
by: Vavouraki, A., et al.
Published: (2008)
by: Vavouraki, A., et al.
Published: (2008)
Hydration effects on the stability of calcium carbonate pre-nucleation species
by: Burgos-Cara, A., et al.
Published: (2017)
by: Burgos-Cara, A., et al.
Published: (2017)
Hydration effects on gypsum dissolution revealed by in situ nanoscale atomic force microscopy observations
by: Burgos-Cara, A., et al.
Published: (2016)
by: Burgos-Cara, A., et al.
Published: (2016)
Microscopic evidence for liquid-liquid separation in supersaturated CaCO3 solutions
by: Wallace, A., et al.
Published: (2013)
by: Wallace, A., et al.
Published: (2013)
Crystal growth and dissolution of calcite in the presence of fluoride ions: An atomic force microscopy study
by: Vavouraki, A., et al.
Published: (2010)
by: Vavouraki, A., et al.
Published: (2010)
The effect of a copolymer inhibitor on baryte precipitation
by: Ruiz-Agudo, C., et al.
Published: (2014)
by: Ruiz-Agudo, C., et al.
Published: (2014)
The mineral-water interface: Where minerals react with the environment
by: Putnis, Christine, et al.
Published: (2013)
by: Putnis, Christine, et al.
Published: (2013)
Exploring the effect of poly(acrylic acid) on pre- and post-nucleation BaSO4 species: New insights into the mechanisms of crystallization control by polyelectrolytes
by: Ruiz-Agudo, C., et al.
Published: (2016)
by: Ruiz-Agudo, C., et al.
Published: (2016)
Strain-induced segmentation of magnesian calcite thin films growing on a calcite substrate
by: Sethmann, I., et al.
Published: (2010)
by: Sethmann, I., et al.
Published: (2010)
Effect of ferrous iron on the nucleation and growth of CaCO3 in slightly basic aqueous solutions
by: Di Lorenzo, F., et al.
Published: (2017)
by: Di Lorenzo, F., et al.
Published: (2017)
Similar Items
-
An atomic force microscopy study of the growth of a calcite surface as a function of calcium/total carbonate concentration ratio in solution at constant supersaturation
by: Perdikouri, C., et al.
Published: (2009) -
Influence of chemical and structural factors on the calcite-calcium oxalate transformation
by: Ruiz-Agudo, E., et al.
Published: (2013) -
Boron incorporation into calcite during growth: Implications for the use of boron in carbonates as a pH proxy
by: Ruiz-Agudo, E., et al.
Published: (2012) -
Template-assisted crystallization of sulfates onto calcite: Implications for the prevention of salt damage
by: Ruiz-Agudo, E., et al.
Published: (2013) -
An atomic force microscopy study of calcite dissolution in saline solutions: The role of magnesium ions
by: Ruiz-Agudo, E., et al.
Published: (2009)