Catalytic efficiency and stability of cobalt hydroxide for decomposition of ozone and p-chloronitrobenzene in water

Cobalt hydroxide, a stable and efficient catalyst prepared in the laboratory, has been successfully used in the decomposition of ozone and trace quantities of p-chloronitrobenzene (pCNB) in water. The cobalt hydroxide was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) a...

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Bibliographic Details
Main Authors: Xu, Z., Chen, Z., Joll, Cynthia, Ben, Y., Shen, J., Tao, H.
Format: Journal Article
Published: Elsevier Science 2009
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/47812
Description
Summary:Cobalt hydroxide, a stable and efficient catalyst prepared in the laboratory, has been successfully used in the decomposition of ozone and trace quantities of p-chloronitrobenzene (pCNB) in water. The cobalt hydroxide was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and the Brunauer-Emmet-Teller (BET) method. The decomposition rate of aqueous ozone was increased by 1.527 times in the presence of cobalt hydroxide. Increasing the catalyst loading from 0 to 500 mg/L increased the removal efficiency of pCNB from 59% to 99%. The catalyst morphology and its composition were found to be unaltered after the catalytic reaction. After five successive recycles, the catalyst remained stable in the catalytic ozonation of pCNB.