Improved molecular weight control in ring-opening metathesis polymerization (ROMP) reactions with ru-based olefin metathesis catalysts using n. donors and acid: a kinetic and mechanistic investigation

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Improved molecular weight control in ring-opening metathesis polymerization (ROMP) reactions with ru-based olefin metathesis catalysts using n. donors and acid: a kinetic and mechanistic investigation

The effect of the addition of H3PO4 on the ROMP activity of cyclooctene (COE) with first- [Cl2(PCy3) 2Ru=CHPh] and second-generation [(H2IMeS)Cl 2(PCy3)Ru=CHPh] Grubbs' catalysts 1 and 4 (Cy = cyclohexyl, Ph = phenyl, Mes = 2,4,6-trimethylphenyl (mesityl)), their inhibited mixtures with 1-methy...

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Bibliographic Details
Main Authors:	Dunbar, M., Balof, S., Labeaud, L., Yu, B., Lowe, Andrew, Valente, E., Schanz, H.
Format:	Journal Article
Published:	Wiley - V C H Verlag GmbH & Co. KGaA 2009
Online Access:	http://hdl.handle.net/20.500.11937/47800

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