Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage

Characterising the changes in fingermark composition as a function of time is of great value for improving fingermark detection capabilities by understanding the processes and circumstances under which target compounds become degraded. In this study, gas chromatography-mass spectrometry was used to...

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Main Authors: Frick, Amanda, Chidlow, Geoff, Goodpaster, J., Lewis, Simon, Van Bronswijk, Wilhelm
Format: Journal Article
Published: Elsevier BV 2016
Online Access:http://hdl.handle.net/20.500.11937/47577
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author Frick, Amanda
Chidlow, Geoff
Goodpaster, J.
Lewis, Simon
Van Bronswijk, Wilhelm
author_facet Frick, Amanda
Chidlow, Geoff
Goodpaster, J.
Lewis, Simon
Van Bronswijk, Wilhelm
author_sort Frick, Amanda
building Curtin Institutional Repository
collection Online Access
description Characterising the changes in fingermark composition as a function of time is of great value for improving fingermark detection capabilities by understanding the processes and circumstances under which target compounds become degraded. In this study, gas chromatography-mass spectrometry was used to monitor relative changes in the lipids from latent fingermarks over 28 days. Principal component analysis of the relative composition of 15 lipids in fingermarks showed that fingermark age was a significant contributor to the variability observed in the data, but that inter-donor variability was also significant. This was attributed principally to changes in the relative amounts of squalene, which rapidly decreased in the fingermarks. It was also observed, however, that most fingermarks exhibited relatively small changes in composition during the first seven days, followed by more rapid changes up to 28 days. Significant inter-donor variation of both initial fingermark composition and the rates and nature of loss processes was observed, which was reflected in the relative projection of samples from different donors. Finally, samples stored with no exposure to light or airflow for 28 days were projected significantly closer to the samples analysed on the day of deposition than those exposed to light, due to the reduced photodegradation rate of squalene.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-475772018-09-10T02:55:54Z Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage Frick, Amanda Chidlow, Geoff Goodpaster, J. Lewis, Simon Van Bronswijk, Wilhelm Characterising the changes in fingermark composition as a function of time is of great value for improving fingermark detection capabilities by understanding the processes and circumstances under which target compounds become degraded. In this study, gas chromatography-mass spectrometry was used to monitor relative changes in the lipids from latent fingermarks over 28 days. Principal component analysis of the relative composition of 15 lipids in fingermarks showed that fingermark age was a significant contributor to the variability observed in the data, but that inter-donor variability was also significant. This was attributed principally to changes in the relative amounts of squalene, which rapidly decreased in the fingermarks. It was also observed, however, that most fingermarks exhibited relatively small changes in composition during the first seven days, followed by more rapid changes up to 28 days. Significant inter-donor variation of both initial fingermark composition and the rates and nature of loss processes was observed, which was reflected in the relative projection of samples from different donors. Finally, samples stored with no exposure to light or airflow for 28 days were projected significantly closer to the samples analysed on the day of deposition than those exposed to light, due to the reduced photodegradation rate of squalene. 2016 Journal Article http://hdl.handle.net/20.500.11937/47577 10.1016/j.forc.2016.09.001 Elsevier BV fulltext
spellingShingle Frick, Amanda
Chidlow, Geoff
Goodpaster, J.
Lewis, Simon
Van Bronswijk, Wilhelm
Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title_full Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title_fullStr Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title_full_unstemmed Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title_short Monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
title_sort monitoring compositional changes of the lipid fraction of fingermark residues deposited on paper during storage
url http://hdl.handle.net/20.500.11937/47577