Surface specific measurements of olivine dissolution by phase-shift interferometry
Natural olivine dissolution and replacement often occurs preferentially along specific crystallographic planes. Thus, olivine reactivity at specific surfaces was examined in situ using phase-shift interferometry, which has a detection limit <10–5 nm/s, by dissolving two smoothed olivine crystal f...
| Main Authors: | , , , |
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| Format: | Journal Article |
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Mineralogical Society of America
2014
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| Online Access: | http://hdl.handle.net/20.500.11937/47410 |
| _version_ | 1848757824835813376 |
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| author | King, H.E. Satoh, H. Tsukamoto, K. Putnis, Andrew |
| author_facet | King, H.E. Satoh, H. Tsukamoto, K. Putnis, Andrew |
| author_sort | King, H.E. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Natural olivine dissolution and replacement often occurs preferentially along specific crystallographic planes. Thus, olivine reactivity at specific surfaces was examined in situ using phase-shift interferometry, which has a detection limit <10–5 nm/s, by dissolving two smoothed olivine crystal faces and a third sample corresponding to a surface that was generated by preferential dissolution along structural defects. The experiments were conducted at 22 °C and ambient pressure in 0.1 M NaCl solutions that were acidified to pHs between 1 and 4 using 0.1 M HCl. These experiments show that olivine dissolution can vary from one surface to another as well as in different areas of the same surface that have similar characteristics. The fastest vertical retreat occurred at the surfaces related to defects. However, only vertical advancement was observed at pH 1 on this surface consistent with the observation of isolated islands on the surface during atomic force microscopy investigations after the experiment. Raman analysis of the precipitated phase showed that it was not one of the thermodynamically stable phases expected from PHREEQC modeling.However, the correlation between the siloxane ring peak of amorphous silica with a similar peak in the precipitate spectrum, in conjunction with previous experimental and natural observations, indicates that the precipitate was a Si-enriched amorphous phase. Therefore, precipitation can facilitate the further dissolution of olivine on this surface as long as it does not completely armor the surface. Precipitate formation on surfaces associated with outcropping defects supports the natural observations of preferential dissolution and serpentinization along these defects implying that the fast dissolution of these surfaces will play a critical role during olivine replacement. In addition, comparison with flow-through experiments indicates that outflow fluid chemistry may provide an incomplete picture of processes occurring during olivine dissolution. |
| first_indexed | 2025-11-14T09:34:14Z |
| format | Journal Article |
| id | curtin-20.500.11937-47410 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:34:14Z |
| publishDate | 2014 |
| publisher | Mineralogical Society of America |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-474102017-10-02T02:28:21Z Surface specific measurements of olivine dissolution by phase-shift interferometry King, H.E. Satoh, H. Tsukamoto, K. Putnis, Andrew precipitation olivine dissolution Interferometry Natural olivine dissolution and replacement often occurs preferentially along specific crystallographic planes. Thus, olivine reactivity at specific surfaces was examined in situ using phase-shift interferometry, which has a detection limit <10–5 nm/s, by dissolving two smoothed olivine crystal faces and a third sample corresponding to a surface that was generated by preferential dissolution along structural defects. The experiments were conducted at 22 °C and ambient pressure in 0.1 M NaCl solutions that were acidified to pHs between 1 and 4 using 0.1 M HCl. These experiments show that olivine dissolution can vary from one surface to another as well as in different areas of the same surface that have similar characteristics. The fastest vertical retreat occurred at the surfaces related to defects. However, only vertical advancement was observed at pH 1 on this surface consistent with the observation of isolated islands on the surface during atomic force microscopy investigations after the experiment. Raman analysis of the precipitated phase showed that it was not one of the thermodynamically stable phases expected from PHREEQC modeling.However, the correlation between the siloxane ring peak of amorphous silica with a similar peak in the precipitate spectrum, in conjunction with previous experimental and natural observations, indicates that the precipitate was a Si-enriched amorphous phase. Therefore, precipitation can facilitate the further dissolution of olivine on this surface as long as it does not completely armor the surface. Precipitate formation on surfaces associated with outcropping defects supports the natural observations of preferential dissolution and serpentinization along these defects implying that the fast dissolution of these surfaces will play a critical role during olivine replacement. In addition, comparison with flow-through experiments indicates that outflow fluid chemistry may provide an incomplete picture of processes occurring during olivine dissolution. 2014 Journal Article http://hdl.handle.net/20.500.11937/47410 10.2138/am.2014.4606 Mineralogical Society of America restricted |
| spellingShingle | precipitation olivine dissolution Interferometry King, H.E. Satoh, H. Tsukamoto, K. Putnis, Andrew Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title | Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title_full | Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title_fullStr | Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title_full_unstemmed | Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title_short | Surface specific measurements of olivine dissolution by phase-shift interferometry |
| title_sort | surface specific measurements of olivine dissolution by phase-shift interferometry |
| topic | precipitation olivine dissolution Interferometry |
| url | http://hdl.handle.net/20.500.11937/47410 |