Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes

Synchrotron FTIR microspectroscopy was used to characterise and assess the chemical diversity of electrocoat primer, primer surfacer and basecoats of automotive paint samples from 75 vehicles representing a range of international car manufacturers. Significant diversity was found in the synchrotron...

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Main Authors: Maric, Mark, Van Bronswijk, Wilhelm, Lewis, Simon, Pitts, K.
Format: Journal Article
Published: Elsevier 2014
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/47387
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author Maric, Mark
Van Bronswijk, Wilhelm
Lewis, Simon
Pitts, K.
author_facet Maric, Mark
Van Bronswijk, Wilhelm
Lewis, Simon
Pitts, K.
author_sort Maric, Mark
building Curtin Institutional Repository
collection Online Access
description Synchrotron FTIR microspectroscopy was used to characterise and assess the chemical diversity of electrocoat primer, primer surfacer and basecoats of automotive paint samples from 75 vehicles representing a range of international car manufacturers. Significant diversity was found in the synchrotron FTIR data from the primer surfacer coats. Classification using principal component analysis revealed 14 discrete groups, which could be associated with the country of manufacture, the specific manufacturer and manufacturing plant, the year of manufacture of the vehicle and in some instances the number of layers in the paint system. The model generated from the primer surfacer was significantly more discriminating than a previous model generated from FTIR analysis of clear coats of the same vehicles. Analysis of the primer surfacer also avoids issues of possible environmental degradation and component migration seen with FTIR analysis of automotive clear coats. Providing such information concerning vehicle origin would aid in the development of investigative leads from the analysis of questioned automotive paint samples located at the scene of a crime or on the body/clothing of a hit and run victim.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-473872017-09-13T14:13:45Z Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes Maric, Mark Van Bronswijk, Wilhelm Lewis, Simon Pitts, K. Automotive paint Forensic science Trace evidence Synchrotron FTIR Primer surfacer Synchrotron FTIR microspectroscopy was used to characterise and assess the chemical diversity of electrocoat primer, primer surfacer and basecoats of automotive paint samples from 75 vehicles representing a range of international car manufacturers. Significant diversity was found in the synchrotron FTIR data from the primer surfacer coats. Classification using principal component analysis revealed 14 discrete groups, which could be associated with the country of manufacture, the specific manufacturer and manufacturing plant, the year of manufacture of the vehicle and in some instances the number of layers in the paint system. The model generated from the primer surfacer was significantly more discriminating than a previous model generated from FTIR analysis of clear coats of the same vehicles. Analysis of the primer surfacer also avoids issues of possible environmental degradation and component migration seen with FTIR analysis of automotive clear coats. Providing such information concerning vehicle origin would aid in the development of investigative leads from the analysis of questioned automotive paint samples located at the scene of a crime or on the body/clothing of a hit and run victim. 2014 Journal Article http://hdl.handle.net/20.500.11937/47387 10.1016/j.talanta.2013.10.016 Elsevier fulltext
spellingShingle Automotive paint
Forensic science
Trace evidence
Synchrotron FTIR
Primer surfacer
Maric, Mark
Van Bronswijk, Wilhelm
Lewis, Simon
Pitts, K.
Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title_full Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title_fullStr Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title_full_unstemmed Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title_short Synchrotron FTIR characterisation of automotive primer surfacer paint coatings for forensic purposes
title_sort synchrotron ftir characterisation of automotive primer surfacer paint coatings for forensic purposes
topic Automotive paint
Forensic science
Trace evidence
Synchrotron FTIR
Primer surfacer
url http://hdl.handle.net/20.500.11937/47387