Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths
© 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards...
| Main Authors: | , , |
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| Format: | Journal Article |
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Royal Society of Chemistry
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/4697 |
| _version_ | 1848744589160087552 |
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| author | Humphries, Terry Sheppard, Drew Buckley, Craig |
| author_facet | Humphries, Terry Sheppard, Drew Buckley, Craig |
| author_sort | Humphries, Terry |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards aiding structural solutions and predicting physical properties of novel complex transition metal hydrides. |
| first_indexed | 2025-11-14T06:03:52Z |
| format | Journal Article |
| id | curtin-20.500.11937-4697 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:03:52Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-46972017-09-13T14:45:09Z Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths Humphries, Terry Sheppard, Drew Buckley, Craig © 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards aiding structural solutions and predicting physical properties of novel complex transition metal hydrides. 2015 Journal Article http://hdl.handle.net/20.500.11937/4697 10.1039/c5cc03654b Royal Society of Chemistry unknown |
| spellingShingle | Humphries, Terry Sheppard, Drew Buckley, Craig Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title | Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title_full | Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title_fullStr | Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title_full_unstemmed | Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title_short | Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths |
| title_sort | complex transition metal hydrides: linear correlation of countercation electronegativity versus t-d bond lengths |
| url | http://hdl.handle.net/20.500.11937/4697 |