Synthesis, thiol-yne "click" photopolymerization, and physical properties of networks derived from novel multifunctional alkynes

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Synthesis, thiol-yne "click" photopolymerization, and physical properties of networks derived from novel multifunctional alkynes

Multifunctional alkynes (2, 3, or 4 ynes per monomer) were prepared utilizing the nucleophile-catalyzed thio-Michael addition reaction from commercially available multifunctional thiols (2, 3, or 4 thiols) and propargyl acrylate. Real-time FTIR (RTIR) and NMR spectroscopies indicate that the conjuga...

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Bibliographic Details
Main Authors:	Chan, J., Shin, J., Hoyle, C., Bowman, C., Lowe, Andrew
Format:	Journal Article
Published:	American Chemical Society 2010
Online Access:	http://hdl.handle.net/20.500.11937/46502

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