Lattice dynamics from force-fields as a technique for mineral physics

Theory and computation play an increasingly important role in the field of mineral physics by allowing the scientist to probe environments, such as the deep Earth, that are challenging or impossible to access extensively by experiment. Quantum mechanical methods are often the technique of choice, us...

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Main Authors: Gale, Julian, Wright, Kathleen
Format: Journal Article
Published: Geochemistry Society Mineralogical Society of America 2010
Online Access:http://hdl.handle.net/20.500.11937/45880
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author Gale, Julian
Wright, Kathleen
author_facet Gale, Julian
Wright, Kathleen
author_sort Gale, Julian
building Curtin Institutional Repository
collection Online Access
description Theory and computation play an increasingly important role in the field of mineral physics by allowing the scientist to probe environments, such as the deep Earth, that are challenging or impossible to access extensively by experiment. Quantum mechanical methods are often the technique of choice, usually based on Kohn-Sham density functional theory as the computationally most practical approach for solids. Although calculations at this level can already be performed on thousands of atoms (Soler et al. 2002; Cankurtaran et al. 2008), the ability to sample nuclear configuration space is often restricted. While density functional theory is typically considered the defacto standard, it is important to remember that with current functionals the results will typically be quantitatively in error with respect to experiment, with occasional qualitative errors (Bilic and Gale 2009). The strength of the method is that the errors are generally systematic and can be anticipated a priori.
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spelling curtin-20.500.11937-458802017-09-13T15:57:25Z Lattice dynamics from force-fields as a technique for mineral physics Gale, Julian Wright, Kathleen Theory and computation play an increasingly important role in the field of mineral physics by allowing the scientist to probe environments, such as the deep Earth, that are challenging or impossible to access extensively by experiment. Quantum mechanical methods are often the technique of choice, usually based on Kohn-Sham density functional theory as the computationally most practical approach for solids. Although calculations at this level can already be performed on thousands of atoms (Soler et al. 2002; Cankurtaran et al. 2008), the ability to sample nuclear configuration space is often restricted. While density functional theory is typically considered the defacto standard, it is important to remember that with current functionals the results will typically be quantitatively in error with respect to experiment, with occasional qualitative errors (Bilic and Gale 2009). The strength of the method is that the errors are generally systematic and can be anticipated a priori. 2010 Journal Article http://hdl.handle.net/20.500.11937/45880 10.2138/rmg.2010.71.18 Geochemistry Society Mineralogical Society of America restricted
spellingShingle Gale, Julian
Wright, Kathleen
Lattice dynamics from force-fields as a technique for mineral physics
title Lattice dynamics from force-fields as a technique for mineral physics
title_full Lattice dynamics from force-fields as a technique for mineral physics
title_fullStr Lattice dynamics from force-fields as a technique for mineral physics
title_full_unstemmed Lattice dynamics from force-fields as a technique for mineral physics
title_short Lattice dynamics from force-fields as a technique for mineral physics
title_sort lattice dynamics from force-fields as a technique for mineral physics
url http://hdl.handle.net/20.500.11937/45880