Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator

Characterisation of the concentrations and potential health risks of chemicals in recycled water is important if this source of water is to be safely used to supplement drinking water sources. This research was conducted to: (i) determine the concentration of volatile organic compounds (VOCs) in sec...

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Main Authors: Rodriguez, C, Linge, Kathryn, Blair, P., Busetti, Francesco, Devine, B., Van Buynder, P., Weinstein, P., Cook, A.
Format: Journal Article
Published: IWA Publishing 2011
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/45745
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author Rodriguez, C
Linge, Kathryn
Blair, P.
Busetti, Francesco
Devine, B.
Van Buynder, P.
Weinstein, P.
Cook, A.
author_facet Rodriguez, C
Linge, Kathryn
Blair, P.
Busetti, Francesco
Devine, B.
Van Buynder, P.
Weinstein, P.
Cook, A.
author_sort Rodriguez, C
building Curtin Institutional Repository
collection Online Access
description Characterisation of the concentrations and potential health risks of chemicals in recycled water is important if this source of water is to be safely used to supplement drinking water sources. This research was conducted to: (i) determine the concentration of volatile organic compounds (VOCs) in secondary treated effluent (STE) and, post-reverse osmosis (RO) treatment and to; (ii) assess the health risk associated with VOCs for indirect potable reuse (IPR). Samples were examined pre and post-RO in one full-scale and one pilot plant in Perth, Western Australia. Risk quotients (RQ) were estimated by expressing the maximum and median concentration as a function of the health value. Of 61 VOCs analysed over a period of three years, twenty one (21) were detected in STE, with 1,4-dichlorobenzene (94%); tetrachloroethene (88%); carbon disulfide (81%) and; chloromethane (58%) most commonly detected. Median concentrations for these compounds in STE ranged from 0.81 μg/L for 1,4-dichlorobenzene to 0.02 μg/L for carbon disulphide. After RO, twenty six (26) VOCs were detected, of which 1,4-dichlorobenzene (89%); acrylonitrile (83%) chloromethane (63%) and carbon disulfide (40%) were the more frequently detected. RQ(max) were all below health values in the STE and after RO. Median removal efficiency for RO was variable, ranging from −77% (dichlorodifluoromethane) to 91.2% (tetrachloroethene).The results indicate that despite the detection of VOCs in STE and after RO, their human health impact in IPR is negligible due to the low concentrations detected. The results indicate that 1,4-dichlorobenzene is a potential treatment chemical indicator for assessment of VOCs in IPR using RO treatment.
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spelling curtin-20.500.11937-457452019-02-19T05:35:17Z Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator Rodriguez, C Linge, Kathryn Blair, P. Busetti, Francesco Devine, B. Van Buynder, P. Weinstein, P. Cook, A. Reverse osmosis Indirect potable reuse Organic pollutants Water recycling Water quality Volatile organic compounds Characterisation of the concentrations and potential health risks of chemicals in recycled water is important if this source of water is to be safely used to supplement drinking water sources. This research was conducted to: (i) determine the concentration of volatile organic compounds (VOCs) in secondary treated effluent (STE) and, post-reverse osmosis (RO) treatment and to; (ii) assess the health risk associated with VOCs for indirect potable reuse (IPR). Samples were examined pre and post-RO in one full-scale and one pilot plant in Perth, Western Australia. Risk quotients (RQ) were estimated by expressing the maximum and median concentration as a function of the health value. Of 61 VOCs analysed over a period of three years, twenty one (21) were detected in STE, with 1,4-dichlorobenzene (94%); tetrachloroethene (88%); carbon disulfide (81%) and; chloromethane (58%) most commonly detected. Median concentrations for these compounds in STE ranged from 0.81 μg/L for 1,4-dichlorobenzene to 0.02 μg/L for carbon disulphide. After RO, twenty six (26) VOCs were detected, of which 1,4-dichlorobenzene (89%); acrylonitrile (83%) chloromethane (63%) and carbon disulfide (40%) were the more frequently detected. RQ(max) were all below health values in the STE and after RO. Median removal efficiency for RO was variable, ranging from −77% (dichlorodifluoromethane) to 91.2% (tetrachloroethene).The results indicate that despite the detection of VOCs in STE and after RO, their human health impact in IPR is negligible due to the low concentrations detected. The results indicate that 1,4-dichlorobenzene is a potential treatment chemical indicator for assessment of VOCs in IPR using RO treatment. 2011 Journal Article http://hdl.handle.net/20.500.11937/45745 10.1016/j.watres.2011.10.032 IWA Publishing fulltext
spellingShingle Reverse osmosis
Indirect potable reuse
Organic pollutants
Water recycling
Water quality
Volatile organic compounds
Rodriguez, C
Linge, Kathryn
Blair, P.
Busetti, Francesco
Devine, B.
Van Buynder, P.
Weinstein, P.
Cook, A.
Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title_full Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title_fullStr Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title_full_unstemmed Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title_short Recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
title_sort recycled water: potential health risks from volatile compounds and the use of 1,4-dichlorobenzene as a treatment performance indicator
topic Reverse osmosis
Indirect potable reuse
Organic pollutants
Water recycling
Water quality
Volatile organic compounds
url http://hdl.handle.net/20.500.11937/45745