The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction

UV–vis spectra, XRD, H2-TPR, TEM and ESR were used to characterize a series of Cu/y-Al2O3 catalysts, which were prepared by incipient wetness impregnation using copper nitrate, copper acetate or copper sulfate as precursors, to study the role of Cu species on Cu/y-Al2O3 catalysts for NH3–SCO reactio...

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Main Authors: Liang, C., Li, Xin Yong, Qu, Z., Tade, Moses, Liu, Shaomin
Format: Journal Article
Published: Elsevier BV North-Holland 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/45589
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author Liang, C.
Li, Xin Yong
Qu, Z.
Tade, Moses
Liu, Shaomin
author_facet Liang, C.
Li, Xin Yong
Qu, Z.
Tade, Moses
Liu, Shaomin
author_sort Liang, C.
building Curtin Institutional Repository
collection Online Access
description UV–vis spectra, XRD, H2-TPR, TEM and ESR were used to characterize a series of Cu/y-Al2O3 catalysts, which were prepared by incipient wetness impregnation using copper nitrate, copper acetate or copper sulfate as precursors, to study the role of Cu species on Cu/y-Al2O3 catalysts for NH3–SCO reaction. It was found that the mixture of CuO phase and CuAl2O4 phase formed on various Cu/y-Al2O3 catalysts, and the Cu species and dispersion had significant influence on the Cu/y-Al2O3 activity. Highly dispersed CuO phase on the support would be related with its high activity for the NH3–SCO reaction.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:26:21Z
publishDate 2012
publisher Elsevier BV North-Holland
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spelling curtin-20.500.11937-455892017-09-13T14:26:11Z The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction Liang, C. Li, Xin Yong Qu, Z. Tade, Moses Liu, Shaomin Copper species NH3–SCO Cu/y-Al2O3 Dispersion UV–vis spectra, XRD, H2-TPR, TEM and ESR were used to characterize a series of Cu/y-Al2O3 catalysts, which were prepared by incipient wetness impregnation using copper nitrate, copper acetate or copper sulfate as precursors, to study the role of Cu species on Cu/y-Al2O3 catalysts for NH3–SCO reaction. It was found that the mixture of CuO phase and CuAl2O4 phase formed on various Cu/y-Al2O3 catalysts, and the Cu species and dispersion had significant influence on the Cu/y-Al2O3 activity. Highly dispersed CuO phase on the support would be related with its high activity for the NH3–SCO reaction. 2012 Journal Article http://hdl.handle.net/20.500.11937/45589 10.1016/j.apsusc.2011.12.017 Elsevier BV North-Holland restricted
spellingShingle Copper species
NH3–SCO
Cu/y-Al2O3
Dispersion
Liang, C.
Li, Xin Yong
Qu, Z.
Tade, Moses
Liu, Shaomin
The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title_full The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title_fullStr The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title_full_unstemmed The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title_short The role of copper species on Cu/[gamma]-Al2O3 catalysts for NH3-SCO reaction
title_sort role of copper species on cu/[gamma]-al2o3 catalysts for nh3-sco reaction
topic Copper species
NH3–SCO
Cu/y-Al2O3
Dispersion
url http://hdl.handle.net/20.500.11937/45589