Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders

Bone-like low elastic modulus micro-porous titanium (Ti) and titanium-zirconia (Ti-ZrO2) nanocomposites were fabricated by a pressureless sintering process with biocompatible polymethyl methacrylate (PMMA) powders as the pore-forming agents. A microstructural analysis revealed that the method can su...

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Main Authors: Gain, A., Zhang, L., Quadir, Md Zakaria
Format: Journal Article
Published: Elsevier S.A. 2016
Online Access:http://hdl.handle.net/20.500.11937/45355
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author Gain, A.
Zhang, L.
Quadir, Md Zakaria
author_facet Gain, A.
Zhang, L.
Quadir, Md Zakaria
author_sort Gain, A.
building Curtin Institutional Repository
collection Online Access
description Bone-like low elastic modulus micro-porous titanium (Ti) and titanium-zirconia (Ti-ZrO2) nanocomposites were fabricated by a pressureless sintering process with biocompatible polymethyl methacrylate (PMMA) powders as the pore-forming agents. A microstructural analysis revealed that the method can successfully make randomly distributed pores in the sintered monolithic and nanocomposite, and the pore-forming agents can be removed by a heat treatment process. The material properties, i.e., the relative density, pore morphology, microhardness and elastic modulus, can be dramatically altered with the pore-forming agent. Moreover, the porous Ti-based nanocomposites produced in this way (50 vol% PMMA) have interconnected pores, higher biocompatibility, better mechanical properties and well controlled the Ti grain size, when compared with the monolithic porous Ti bodies through the second phase strengthening mechanism. The elastic moduli of the highly porous monolithic Ti and Ti-ZrO2 nanocomposites can be controlled to be about 20.0 and 22.4 GPa, respectively, which are almost the same as human cortical bones (7-25 GPa).
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spelling curtin-20.500.11937-453552017-09-13T14:22:14Z Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders Gain, A. Zhang, L. Quadir, Md Zakaria Bone-like low elastic modulus micro-porous titanium (Ti) and titanium-zirconia (Ti-ZrO2) nanocomposites were fabricated by a pressureless sintering process with biocompatible polymethyl methacrylate (PMMA) powders as the pore-forming agents. A microstructural analysis revealed that the method can successfully make randomly distributed pores in the sintered monolithic and nanocomposite, and the pore-forming agents can be removed by a heat treatment process. The material properties, i.e., the relative density, pore morphology, microhardness and elastic modulus, can be dramatically altered with the pore-forming agent. Moreover, the porous Ti-based nanocomposites produced in this way (50 vol% PMMA) have interconnected pores, higher biocompatibility, better mechanical properties and well controlled the Ti grain size, when compared with the monolithic porous Ti bodies through the second phase strengthening mechanism. The elastic moduli of the highly porous monolithic Ti and Ti-ZrO2 nanocomposites can be controlled to be about 20.0 and 22.4 GPa, respectively, which are almost the same as human cortical bones (7-25 GPa). 2016 Journal Article http://hdl.handle.net/20.500.11937/45355 10.1016/j.msea.2016.03.066 Elsevier S.A. restricted
spellingShingle Gain, A.
Zhang, L.
Quadir, Md Zakaria
Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title_full Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title_fullStr Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title_full_unstemmed Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title_short Composites matching the properties of human cortical bones: The design of porous titanium-zirconia (Ti-ZrO2) nanocomposites using polymethyl methacrylate powders
title_sort composites matching the properties of human cortical bones: the design of porous titanium-zirconia (ti-zro2) nanocomposites using polymethyl methacrylate powders
url http://hdl.handle.net/20.500.11937/45355