Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces

In this paper, we present our preliminary studies into naphthoquinones as novel reagents for the detection of latent fingermarks on paper. Latent fingermarks deposited on paper substrates were treated with solutions of selected naphthoquinones in ethyl acetate/HFE-7100, with subsequent heating. The...

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Main Authors: Jelly, R., Lewis, Simon, Lennard, C., Lim, K., Almog, J.
Format: Journal Article
Published: Elsevier 2010
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/44868
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author Jelly, R.
Lewis, Simon
Lennard, C.
Lim, K.
Almog, J.
author_facet Jelly, R.
Lewis, Simon
Lennard, C.
Lim, K.
Almog, J.
author_sort Jelly, R.
building Curtin Institutional Repository
collection Online Access
description In this paper, we present our preliminary studies into naphthoquinones as novel reagents for the detection of latent fingermarks on paper. Latent fingermarks deposited on paper substrates were treated with solutions of selected naphthoquinones in ethyl acetate/HFE-7100, with subsequent heating. The selected compounds were 1,4-dihydroxy-2-naphthoic acid, 1,2-naphthoquinone- 4-sulfonate, 2-methoxy-1,4-naphthoquinone and 2-methyl-1,4-naphthoquinone. All of the tested compounds yielded purple-brown visible fingermarks, which also exhibited photoluminescence when illuminated with a high intensity filtered light source at 555nm and viewed through red goggles. Indirect heat using an oven at 150 C for1 h was found to be superior to direct heat with an iron, which while providing faster development lead to increased levels of background colouration. Luminescence spectrophotometry revealed differences in photoluminescence characteristics for fingermarks developed with the different naphthoquinones, with excitation over the range 530-590 nm. Luminescence spectrophotometry of developed lysine, glycine and serine spots on paper was used to confirm that the naphthoquinones were reacting with amino acids in the latent fingermark.
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spelling curtin-20.500.11937-448682017-09-13T15:59:55Z Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces Jelly, R. Lewis, Simon Lennard, C. Lim, K. Almog, J. Amino acids Naphthoquinones Forensic science Fingerprints Latent fingermarks Paper surfaces In this paper, we present our preliminary studies into naphthoquinones as novel reagents for the detection of latent fingermarks on paper. Latent fingermarks deposited on paper substrates were treated with solutions of selected naphthoquinones in ethyl acetate/HFE-7100, with subsequent heating. The selected compounds were 1,4-dihydroxy-2-naphthoic acid, 1,2-naphthoquinone- 4-sulfonate, 2-methoxy-1,4-naphthoquinone and 2-methyl-1,4-naphthoquinone. All of the tested compounds yielded purple-brown visible fingermarks, which also exhibited photoluminescence when illuminated with a high intensity filtered light source at 555nm and viewed through red goggles. Indirect heat using an oven at 150 C for1 h was found to be superior to direct heat with an iron, which while providing faster development lead to increased levels of background colouration. Luminescence spectrophotometry revealed differences in photoluminescence characteristics for fingermarks developed with the different naphthoquinones, with excitation over the range 530-590 nm. Luminescence spectrophotometry of developed lysine, glycine and serine spots on paper was used to confirm that the naphthoquinones were reacting with amino acids in the latent fingermark. 2010 Journal Article http://hdl.handle.net/20.500.11937/44868 10.1016/j.talanta.2010.07.064 Elsevier fulltext
spellingShingle Amino acids
Naphthoquinones
Forensic science
Fingerprints
Latent fingermarks
Paper surfaces
Jelly, R.
Lewis, Simon
Lennard, C.
Lim, K.
Almog, J.
Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title_full Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title_fullStr Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title_full_unstemmed Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title_short Substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
title_sort substituted naphthoquinones as novel amino acid sensitive reagents for the detection of latent fingermarks on paper surfaces
topic Amino acids
Naphthoquinones
Forensic science
Fingerprints
Latent fingermarks
Paper surfaces
url http://hdl.handle.net/20.500.11937/44868