7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate.
7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine crystallized with one molecule of methanol to give the title compound, C12H13N7CH3OH. The triazolo[1,5-a][1,3,5]triazine heterocyclic core is essentially planar as are both amino groups that are involved in -electron delocalization...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
Blackwell Munksgaard
2008
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| Online Access: | http://hdl.handle.net/20.500.11937/4486 |
| _version_ | 1848744529484578816 |
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| author | Dolzhenko, Anton Tan, G. Koh, L. Woo, S. Chui, W. |
| author_facet | Dolzhenko, Anton Tan, G. Koh, L. Woo, S. Chui, W. |
| author_sort | Dolzhenko, Anton |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine crystallized with one molecule of methanol to give the title compound, C12H13N7CH3OH. The triazolo[1,5-a][1,3,5]triazine heterocyclic core is essentially planar as are both amino groups that are involved in -electron delocalization with the triazolo[1,5-a][1,3,5]triazine nucleus. The methyl groups of the dimethylamino fragment are involved in the formation of weak intramolecular C-H...N hydrogen bonds with the N atoms of the heterocyclic system. The crystal packing is stabilized by intermolecular N-H...N hydrogen bonds between the triazolo[1,5-a][1,3,5]triazine molecules. The methanol solvent molecule also participates in the formation of the crystal structure via intermolecular O-H...N, N-H...O and weak C-H...O hydrogen bonds, linking the layers of triazolo[1,5-a][1,3,5]triazine molecules. |
| first_indexed | 2025-11-14T06:02:55Z |
| format | Journal Article |
| id | curtin-20.500.11937-4486 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:02:55Z |
| publishDate | 2008 |
| publisher | Blackwell Munksgaard |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-44862017-09-13T16:06:09Z 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. Dolzhenko, Anton Tan, G. Koh, L. Woo, S. Chui, W. 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine crystallized with one molecule of methanol to give the title compound, C12H13N7CH3OH. The triazolo[1,5-a][1,3,5]triazine heterocyclic core is essentially planar as are both amino groups that are involved in -electron delocalization with the triazolo[1,5-a][1,3,5]triazine nucleus. The methyl groups of the dimethylamino fragment are involved in the formation of weak intramolecular C-H...N hydrogen bonds with the N atoms of the heterocyclic system. The crystal packing is stabilized by intermolecular N-H...N hydrogen bonds between the triazolo[1,5-a][1,3,5]triazine molecules. The methanol solvent molecule also participates in the formation of the crystal structure via intermolecular O-H...N, N-H...O and weak C-H...O hydrogen bonds, linking the layers of triazolo[1,5-a][1,3,5]triazine molecules. 2008 Journal Article http://hdl.handle.net/20.500.11937/4486 10.1107/S1600536808030481 Blackwell Munksgaard fulltext |
| spellingShingle | Dolzhenko, Anton Tan, G. Koh, L. Woo, S. Chui, W. 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title_full | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title_fullStr | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title_full_unstemmed | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title_short | 7-Dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| title_sort | 7-dimethylamino-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol solvate. |
| url | http://hdl.handle.net/20.500.11937/4486 |