Purification of single-walled carbon nanotubes

We present a study of purification of single-walled carbon nanotubes (SWCNTs) using different oxidation temperatures and chemical treatments. We have developed a simple two annealing-steps procedure resulting in high nanotube purity with minimal sample loss. The process involves annealing the SWCNTs...

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Main Authors: Yaya, A., Ewels, C., Wagner, Ph., Suarez-Martinez, Irene, Tekley, G., Jensen, L.R.
Format: Journal Article
Published: Cambridge University Press 2011
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/44548
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author Yaya, A.
Ewels, C.
Wagner, Ph.
Suarez-Martinez, Irene
Tekley, G.
Jensen, L.R.
author_facet Yaya, A.
Ewels, C.
Wagner, Ph.
Suarez-Martinez, Irene
Tekley, G.
Jensen, L.R.
author_sort Yaya, A.
building Curtin Institutional Repository
collection Online Access
description We present a study of purification of single-walled carbon nanotubes (SWCNTs) using different oxidation temperatures and chemical treatments. We have developed a simple two annealing-steps procedure resulting in high nanotube purity with minimal sample loss. The process involves annealing the SWCNTs at 300˚C for 2 h with subsequent reflux in 6 M HCl at 130˚C, followed by further annealing at 350˚C for 1 h with reflux in 6 M HCl at 130˚C. The process results in effective removal of carbon impurities and metal particles which are associated with SWCNTs production. The process is less time-consuming (complete in 4.5 h) than conventional acid purification methods which require over 5 h, and less destructive than conventional methods with a yield of 26%. SWCNT purity was assessed using Raman spectroscopy, thermogravimetry and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy.
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spelling curtin-20.500.11937-445482017-09-13T15:58:40Z Purification of single-walled carbon nanotubes Yaya, A. Ewels, C. Wagner, Ph. Suarez-Martinez, Irene Tekley, G. Jensen, L.R. single-walled carbon nanotubes nanotubes purification We present a study of purification of single-walled carbon nanotubes (SWCNTs) using different oxidation temperatures and chemical treatments. We have developed a simple two annealing-steps procedure resulting in high nanotube purity with minimal sample loss. The process involves annealing the SWCNTs at 300˚C for 2 h with subsequent reflux in 6 M HCl at 130˚C, followed by further annealing at 350˚C for 1 h with reflux in 6 M HCl at 130˚C. The process results in effective removal of carbon impurities and metal particles which are associated with SWCNTs production. The process is less time-consuming (complete in 4.5 h) than conventional acid purification methods which require over 5 h, and less destructive than conventional methods with a yield of 26%. SWCNT purity was assessed using Raman spectroscopy, thermogravimetry and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. 2011 Journal Article http://hdl.handle.net/20.500.11937/44548 10.1051/epjap/2011100482 Cambridge University Press fulltext
spellingShingle single-walled carbon nanotubes
nanotubes
purification
Yaya, A.
Ewels, C.
Wagner, Ph.
Suarez-Martinez, Irene
Tekley, G.
Jensen, L.R.
Purification of single-walled carbon nanotubes
title Purification of single-walled carbon nanotubes
title_full Purification of single-walled carbon nanotubes
title_fullStr Purification of single-walled carbon nanotubes
title_full_unstemmed Purification of single-walled carbon nanotubes
title_short Purification of single-walled carbon nanotubes
title_sort purification of single-walled carbon nanotubes
topic single-walled carbon nanotubes
nanotubes
purification
url http://hdl.handle.net/20.500.11937/44548