Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity

The wetting characteristics of CO2 in rock are of vital importance in carbon geo-storage as they determine fluid dynamics and storage capacities. However, the current literature data has a high uncertainty, which translates into uncertain predictions in terms of containment security and economic pro...

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Main Authors: Al-Yaseri, A., Lebedev, Maxim, Barifcani, A., Iglauer, S.
Format: Journal Article
Published: Academic Press 2015
Online Access:http://hdl.handle.net/20.500.11937/44189
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author Al-Yaseri, A.
Lebedev, Maxim
Barifcani, A.
Iglauer, S.
author_facet Al-Yaseri, A.
Lebedev, Maxim
Barifcani, A.
Iglauer, S.
author_sort Al-Yaseri, A.
building Curtin Institutional Repository
collection Online Access
description The wetting characteristics of CO2 in rock are of vital importance in carbon geo-storage as they determine fluid dynamics and storage capacities. However, the current literature data has a high uncertainty, which translates into uncertain predictions in terms of containment security and economic project feasibility. We thus measured contact angles for the CO2/water/quartz system at relevant reservoir conditions, and analysed the effects of pressure (0.1 to 20) MPa, temperature (296 to 343) K, surface roughness (56 to 1300) nm, salt type (NaCl, CaCl2, and MgCl2) and brine salinities (0 to 35) wt%. Water contact angles decreased with surface roughness, but increased with pressure, temperature, and brine salinity. Overall the contact angles were significantly increased at storage conditions (~50°) when compared to ambient conditions (always 0°). Consequently quartz is weakly water-wet (not completely water-wet) at storage conditions, and structural and residual trapping capacities are reduced accordingly.
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spelling curtin-20.500.11937-441892017-09-13T14:29:23Z Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity Al-Yaseri, A. Lebedev, Maxim Barifcani, A. Iglauer, S. The wetting characteristics of CO2 in rock are of vital importance in carbon geo-storage as they determine fluid dynamics and storage capacities. However, the current literature data has a high uncertainty, which translates into uncertain predictions in terms of containment security and economic project feasibility. We thus measured contact angles for the CO2/water/quartz system at relevant reservoir conditions, and analysed the effects of pressure (0.1 to 20) MPa, temperature (296 to 343) K, surface roughness (56 to 1300) nm, salt type (NaCl, CaCl2, and MgCl2) and brine salinities (0 to 35) wt%. Water contact angles decreased with surface roughness, but increased with pressure, temperature, and brine salinity. Overall the contact angles were significantly increased at storage conditions (~50°) when compared to ambient conditions (always 0°). Consequently quartz is weakly water-wet (not completely water-wet) at storage conditions, and structural and residual trapping capacities are reduced accordingly. 2015 Journal Article http://hdl.handle.net/20.500.11937/44189 10.1016/j.jct.2015.07.031 Academic Press restricted
spellingShingle Al-Yaseri, A.
Lebedev, Maxim
Barifcani, A.
Iglauer, S.
Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title_full Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title_fullStr Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title_full_unstemmed Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title_short Receding and advancing (CO2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
title_sort receding and advancing (co2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity
url http://hdl.handle.net/20.500.11937/44189