Phosphonate additives do not always inhibit crystallization
This paper investigates crystal growth modifiers based on 1,3,5-substituted benzene derivatives. The results show that as expected, the phosphonated derivative inhibits calcite precipitation to a much greater degree than the analogous sulfonate. However, on barium sulfate, both molecules show some c...
| Main Authors: | , , , , , , , |
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| Format: | Journal Article |
| Published: |
The Royal Society of Chemistry
2010
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| Online Access: | http://hdl.handle.net/20.500.11937/44113 |
| _version_ | 1848756904582447104 |
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| author | Baynton, A. Chandler, B. Jones, Franca Nealon, Gareth Ogden, Mark Radomirovic, Tomoko Shimizu, G. Taylor, J. |
| author_facet | Baynton, A. Chandler, B. Jones, Franca Nealon, Gareth Ogden, Mark Radomirovic, Tomoko Shimizu, G. Taylor, J. |
| author_sort | Baynton, A. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | This paper investigates crystal growth modifiers based on 1,3,5-substituted benzene derivatives. The results show that as expected, the phosphonated derivative inhibits calcite precipitation to a much greater degree than the analogous sulfonate. However, on barium sulfate, both molecules show some crystallization promotion behaviour, with the phosphonate being the more potent promoter overall. Thus, the functional group alone does not determine the impact the organic molecule will have on crystallization. This opens the way for additives that have dual purposes (inhibiting the crystallization of one phase while not impacting or promoting the crystallization of other phases). |
| first_indexed | 2025-11-14T09:19:37Z |
| format | Journal Article |
| id | curtin-20.500.11937-44113 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:19:37Z |
| publishDate | 2010 |
| publisher | The Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-441132018-03-12T01:02:41Z Phosphonate additives do not always inhibit crystallization Baynton, A. Chandler, B. Jones, Franca Nealon, Gareth Ogden, Mark Radomirovic, Tomoko Shimizu, G. Taylor, J. This paper investigates crystal growth modifiers based on 1,3,5-substituted benzene derivatives. The results show that as expected, the phosphonated derivative inhibits calcite precipitation to a much greater degree than the analogous sulfonate. However, on barium sulfate, both molecules show some crystallization promotion behaviour, with the phosphonate being the more potent promoter overall. Thus, the functional group alone does not determine the impact the organic molecule will have on crystallization. This opens the way for additives that have dual purposes (inhibiting the crystallization of one phase while not impacting or promoting the crystallization of other phases). 2010 Journal Article http://hdl.handle.net/20.500.11937/44113 10.1039/C0CE00338G The Royal Society of Chemistry fulltext |
| spellingShingle | Baynton, A. Chandler, B. Jones, Franca Nealon, Gareth Ogden, Mark Radomirovic, Tomoko Shimizu, G. Taylor, J. Phosphonate additives do not always inhibit crystallization |
| title | Phosphonate additives do not always inhibit crystallization |
| title_full | Phosphonate additives do not always inhibit crystallization |
| title_fullStr | Phosphonate additives do not always inhibit crystallization |
| title_full_unstemmed | Phosphonate additives do not always inhibit crystallization |
| title_short | Phosphonate additives do not always inhibit crystallization |
| title_sort | phosphonate additives do not always inhibit crystallization |
| url | http://hdl.handle.net/20.500.11937/44113 |