Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry

A solid-phase extraction (SPE) LC/MS/MS method for 18 commercial drugs in secondary wastewaterand product water from water recycling plants using microfiltration (MF) and reverse osmosis (RO)has been developed, optimised and validated. The method incorporates a range of multi-class pharmaceuticals i...

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Main Authors: Busetti, Francesco, Linge, Kathryn, Heitz, Anna
Format: Journal Article
Published: Elsevier 2009
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/44005
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author Busetti, Francesco
Linge, Kathryn
Heitz, Anna
author_facet Busetti, Francesco
Linge, Kathryn
Heitz, Anna
author_sort Busetti, Francesco
building Curtin Institutional Repository
collection Online Access
description A solid-phase extraction (SPE) LC/MS/MS method for 18 commercial drugs in secondary wastewaterand product water from water recycling plants using microfiltration (MF) and reverse osmosis (RO)has been developed, optimised and validated. The method incorporates a range of multi-class pharmaceuticals including lipid lowering agents, analgesics, antipyretics, non-steroidal anti-inflammatory drugs, antidepressants, anticoagulants, tranquilizers, cytostatic agents, and antiepileptics. Method limits of quantitation (MLQs) in secondary wastewater ranged from 15 to 250 ng/L, while MLQs in post-RO water ranged from1 to 25 ng/L. Results fromanalysis of secondary waste water from Western Australia are presented, and represent the largest survey of non-antibiotic pharmaceuticals within Australia to date. Analysis of post-RO water from two MF/RO water recycling facilities also demonstrate that MF/RO treatment removes most pharmaceuticals to below the analytical limits of detection, and more importantly, up to seven orders of magnitude below health-based guideline values.
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spelling curtin-20.500.11937-440052017-09-13T16:05:30Z Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry Busetti, Francesco Linge, Kathryn Heitz, Anna LC-MS wastewater water reuse pharmaceuticals indirect potable reuse systems solid-phase extraction (SPE) reverse osmosis A solid-phase extraction (SPE) LC/MS/MS method for 18 commercial drugs in secondary wastewaterand product water from water recycling plants using microfiltration (MF) and reverse osmosis (RO)has been developed, optimised and validated. The method incorporates a range of multi-class pharmaceuticals including lipid lowering agents, analgesics, antipyretics, non-steroidal anti-inflammatory drugs, antidepressants, anticoagulants, tranquilizers, cytostatic agents, and antiepileptics. Method limits of quantitation (MLQs) in secondary wastewater ranged from 15 to 250 ng/L, while MLQs in post-RO water ranged from1 to 25 ng/L. Results fromanalysis of secondary waste water from Western Australia are presented, and represent the largest survey of non-antibiotic pharmaceuticals within Australia to date. Analysis of post-RO water from two MF/RO water recycling facilities also demonstrate that MF/RO treatment removes most pharmaceuticals to below the analytical limits of detection, and more importantly, up to seven orders of magnitude below health-based guideline values. 2009 Journal Article http://hdl.handle.net/20.500.11937/44005 10.1016/j.chroma.2009.06.001 Elsevier restricted
spellingShingle LC-MS
wastewater
water reuse
pharmaceuticals
indirect potable reuse systems
solid-phase extraction (SPE)
reverse osmosis
Busetti, Francesco
Linge, Kathryn
Heitz, Anna
Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title_full Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title_fullStr Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title_full_unstemmed Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title_short Analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
title_sort analysis of pharmaceuticals in indirect potable reuse systems using solid-phase extraction and liquid chromatography-tandem mass spectrometry
topic LC-MS
wastewater
water reuse
pharmaceuticals
indirect potable reuse systems
solid-phase extraction (SPE)
reverse osmosis
url http://hdl.handle.net/20.500.11937/44005