Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals

Transparent oxyfluoride borosilicate glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals were successfully prepared by a melt-quenching method with subsequent heat treatment. The precipitated crystalline phase in the glass matrix changed gradually from BaF 2 to Ba 2+1.5xYb 1-xF 7 with th...

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Main Authors: Xin, F., Zhao, S., Jia, Guohua, Huang, L., Deng, D., Wang, H., Xu, S.
Format: Journal Article
Published: Elsevier 2012
Online Access:http://hdl.handle.net/20.500.11937/43723
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author Xin, F.
Zhao, S.
Jia, Guohua
Huang, L.
Deng, D.
Wang, H.
Xu, S.
author_facet Xin, F.
Zhao, S.
Jia, Guohua
Huang, L.
Deng, D.
Wang, H.
Xu, S.
author_sort Xin, F.
building Curtin Institutional Repository
collection Online Access
description Transparent oxyfluoride borosilicate glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals were successfully prepared by a melt-quenching method with subsequent heat treatment. The precipitated crystalline phase in the glass matrix changed gradually from BaF 2 to Ba 2+1.5xYb 1-xF 7 with the increase of YbF 3 content, which was confirmed by the results of XRD, HRTEM and EDX measurements. The ultraviolet and visible up-conversion and near-infrared quantum cutting down-conversion emissions were observed and interpreted. These materials could be used to modify the solar spectrum and enhance the silicon solar cell efficiency by the up-conversion and down-conversion luminescence of Tb 3+-Yb 3+ couples in the oxyfluoride borosilicate glass ceramics. © 2012 Elsevier B.V. All rights reserved.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:17:45Z
publishDate 2012
publisher Elsevier
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spelling curtin-20.500.11937-437232017-09-13T13:37:33Z Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals Xin, F. Zhao, S. Jia, Guohua Huang, L. Deng, D. Wang, H. Xu, S. Transparent oxyfluoride borosilicate glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals were successfully prepared by a melt-quenching method with subsequent heat treatment. The precipitated crystalline phase in the glass matrix changed gradually from BaF 2 to Ba 2+1.5xYb 1-xF 7 with the increase of YbF 3 content, which was confirmed by the results of XRD, HRTEM and EDX measurements. The ultraviolet and visible up-conversion and near-infrared quantum cutting down-conversion emissions were observed and interpreted. These materials could be used to modify the solar spectrum and enhance the silicon solar cell efficiency by the up-conversion and down-conversion luminescence of Tb 3+-Yb 3+ couples in the oxyfluoride borosilicate glass ceramics. © 2012 Elsevier B.V. All rights reserved. 2012 Journal Article http://hdl.handle.net/20.500.11937/43723 10.1016/j.matchemphys.2012.09.002 Elsevier restricted
spellingShingle Xin, F.
Zhao, S.
Jia, Guohua
Huang, L.
Deng, D.
Wang, H.
Xu, S.
Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title_full Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title_fullStr Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title_full_unstemmed Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title_short Up- and down-conversion luminescence in the oxyfluoride glass ceramics containing Ba 2+1.5xYb 1-xF 7:Tb 3+ nanocrystals
title_sort up- and down-conversion luminescence in the oxyfluoride glass ceramics containing ba 2+1.5xyb 1-xf 7:tb 3+ nanocrystals
url http://hdl.handle.net/20.500.11937/43723