Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light

Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes (AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide (g-C3N4/TiO2) composites were synthesized by a facile sonication method. The physicoche...

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Main Authors: Song, G., Chu, Z., Jin, W., Sun, Hongqi
Format: Journal Article
Published: Chemical Industry Press 2015
Online Access:http://hdl.handle.net/20.500.11937/43672
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author Song, G.
Chu, Z.
Jin, W.
Sun, Hongqi
author_facet Song, G.
Chu, Z.
Jin, W.
Sun, Hongqi
author_sort Song, G.
building Curtin Institutional Repository
collection Online Access
description Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes (AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide (g-C3N4/TiO2) composites were synthesized by a facile sonication method. The physicochemical properties of the photocatalyst with different mass ratios of g-C3N4 to TiO2 were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), N2 sorption, Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and UV–vis DRS. The photocatalytic performances were evaluated by degradation of methylene blue. It was found that g-C3N4/TiO2 with a mass ratio of 1.5:1 exhibited the best degradation performance. Under UV, the degradation rate of g-C3N4/TiO2 was 6.92 and 2.65 times higher than g-C3N4 and TiO2, respectively. While under visible light, the enhancement factors became 9.27 (to g-C3N4) and 7.03 (to TiO2). The improved photocatalytic activity was ascribed to the interfacial charge transfer between g-C3N4 and TiO2. This work suggests that hybridization can produce promising solar materials for environmental remediation.
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spelling curtin-20.500.11937-436722017-09-13T13:39:38Z Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light Song, G. Chu, Z. Jin, W. Sun, Hongqi Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes (AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide (g-C3N4/TiO2) composites were synthesized by a facile sonication method. The physicochemical properties of the photocatalyst with different mass ratios of g-C3N4 to TiO2 were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), N2 sorption, Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and UV–vis DRS. The photocatalytic performances were evaluated by degradation of methylene blue. It was found that g-C3N4/TiO2 with a mass ratio of 1.5:1 exhibited the best degradation performance. Under UV, the degradation rate of g-C3N4/TiO2 was 6.92 and 2.65 times higher than g-C3N4 and TiO2, respectively. While under visible light, the enhancement factors became 9.27 (to g-C3N4) and 7.03 (to TiO2). The improved photocatalytic activity was ascribed to the interfacial charge transfer between g-C3N4 and TiO2. This work suggests that hybridization can produce promising solar materials for environmental remediation. 2015 Journal Article http://hdl.handle.net/20.500.11937/43672 10.1016/j.cjche.2015.05.003 Chemical Industry Press restricted
spellingShingle Song, G.
Chu, Z.
Jin, W.
Sun, Hongqi
Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title_full Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title_fullStr Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title_full_unstemmed Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title_short Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light
title_sort enhanced performance of g-c3n4/tio2 photocatalysts for degradation of organic pollutants under visible light
url http://hdl.handle.net/20.500.11937/43672