Structural and Photophysical Investigation of Lanthanoid β-Triketonates

Reaction of β-triketonate ligands with lanthanoid cations in the presence of different bases results in the formation of structurally unique mononuclear and tetranuclear lanthanoid- species. The photophysical properties of the species were assessed in solid-state and solution, revealing bright visib...

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Main Author: Reid, Brodie Lionel
Format: Thesis
Language:English
Published: Curtin University 2015
Online Access:http://hdl.handle.net/20.500.11937/434
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author Reid, Brodie Lionel
author_facet Reid, Brodie Lionel
author_sort Reid, Brodie Lionel
building Curtin Institutional Repository
collection Online Access
description Reaction of β-triketonate ligands with lanthanoid cations in the presence of different bases results in the formation of structurally unique mononuclear and tetranuclear lanthanoid- species. The photophysical properties of the species were assessed in solid-state and solution, revealing bright visible or near infrared (NIR) emission. The NIR emission in particular was applied to the fabrication of a working NIR-organic light-emitting device (OLED). An α-nitrile β-diketonate Eu3+ complex was also investigated structurally, and spectroscopically.
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spelling curtin-20.500.11937-4342017-02-20T06:42:28Z Structural and Photophysical Investigation of Lanthanoid β-Triketonates Reid, Brodie Lionel Reaction of β-triketonate ligands with lanthanoid cations in the presence of different bases results in the formation of structurally unique mononuclear and tetranuclear lanthanoid- species. The photophysical properties of the species were assessed in solid-state and solution, revealing bright visible or near infrared (NIR) emission. The NIR emission in particular was applied to the fabrication of a working NIR-organic light-emitting device (OLED). An α-nitrile β-diketonate Eu3+ complex was also investigated structurally, and spectroscopically. 2015 Thesis http://hdl.handle.net/20.500.11937/434 en Curtin University fulltext
spellingShingle Reid, Brodie Lionel
Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title_full Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title_fullStr Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title_full_unstemmed Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title_short Structural and Photophysical Investigation of Lanthanoid β-Triketonates
title_sort structural and photophysical investigation of lanthanoid β-triketonates
url http://hdl.handle.net/20.500.11937/434