Structure and decomposition of zinc borohydride ammonia adduct: towards a pure hydrogen release

Structure and decomposition of zinc borohydride ammonia adduct: towards a pure hydrogen release

Zn(BH4)2.2NH3, a new ammine metal borohydride, has been synthesized via simply ball-milling a mixture of ZnCl2.2NH3/2LiBH4. Structure analysis shows that the subsequent complex has a monoclinic structure with unit-cell parameters of a = 6.392(4) A, b = 8.417(6) A, c = 6.388(4) A and β = 92.407(4)° a...

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Bibliographic Details
Main Authors: Gu, Q., Gao, L., Guo, Y., Tan, Y., Tang, Z., Wallwork, K., Zhang, Feiwu, Yu, X.
Format: Journal Article
Published: Royal Society of Chemistry 2012
Online Access:http://hdl.handle.net/20.500.11937/43259

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