Formation of Ho-III Trinuclear Clusters and Gd-III Monodimensional Polymers Induced by ortho and para Regioisomers of Pyridyl-Functionalised beta-Diketones: Synthesis, Structure, and Magnetic Properties

Formation of Ho-III Trinuclear Clusters and Gd-III Monodimensional Polymers Induced by ortho and para Regioisomers of Pyridyl-Functionalised beta-Diketones: Synthesis, Structure, and Magnetic Properties

Reaction of GdCl3(H2O)(6) and 1,3-bis(pyridin-4-yl)propane-1,3-dione in methanol with an excess of triethylamine produced a monodimensional polymeric chain [Gd(p-dppd)(3)-(H2O)](infinity), whereas treatment of HoCl3(H2O)(6) with 1,3-bis(pyridin-2-yl)propane-1,3-dione yielded a trinuclear cluster [Ho...

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Bibliographic Details
Main Authors: Andrews, P., Deacon, G., Frank, R., Fraser, B., Junk, P., Maclellan, J., Massi, Massimiliano, Moubaraki, B., Murray, K., Silberstein, Morry
Format: Journal Article
Published: Wiley-VCH Verlag GmbH & Co 2009
Subjects:
LINKERS
LIGANDS
LANTHANIDE CLUSTERS
N
COORDINATION POLYMERS
CUBANE CLUSTERS
Coordination polymers
O ligands
DYSPROSIUM TRIANGLES
Cluster compounds
SURFACE
Ketones
CHEMISTRY
beta-Diketonate ligands
Molecular magnets
Chelates
TETRANUCLEAR
COMPLEXES
Online Access:http://hdl.handle.net/20.500.11937/42842

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