Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells

The effect of an amorphous TiOx interlayer on layered graphene/quantum dots photochemical cells has been investigated. The addition of the TiOx interlayer eliminates the decay of photocurrent in the initial seconds after light illumination and significantly increases the slope of the steady-state ph...

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Main Authors: Yang, H., Guo, C., Guai, G., Song, Q., Jiang, San Ping, Li, C.
Format: Journal Article
Published: American Chemical Society 2011
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/41348
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author Yang, H.
Guo, C.
Guai, G.
Song, Q.
Jiang, San Ping
Li, C.
author_facet Yang, H.
Guo, C.
Guai, G.
Song, Q.
Jiang, San Ping
Li, C.
author_sort Yang, H.
building Curtin Institutional Repository
collection Online Access
description The effect of an amorphous TiOx interlayer on layered graphene/quantum dots photochemical cells has been investigated. The addition of the TiOx interlayer eliminates the decay of photocurrent in the initial seconds after light illumination and significantly increases the slope of the steady-state photocurrent versus the light intensity. The open-circuit voltage decay measurements further illustrate a longer electron lifetime when an amorphous TiOx interlayer is applied. Consequently, the photocurrent and photovoltage of the photovoltaic cell with a TiOx interlayer are greatly increased. This work emonstrates that the graphene/amorphous TiOx composite structure effectively inhibits charge recombination while enhancing charge transfer, providing a promising scaffold for quantum dots and dye-sensitized photovoltaic cells.
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institution Curtin University Malaysia
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publishDate 2011
publisher American Chemical Society
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spelling curtin-20.500.11937-413482017-02-28T01:37:52Z Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells Yang, H. Guo, C. Guai, G. Song, Q. Jiang, San Ping Li, C. quantum dots graphene recombination photochemistry photovoltaic cells The effect of an amorphous TiOx interlayer on layered graphene/quantum dots photochemical cells has been investigated. The addition of the TiOx interlayer eliminates the decay of photocurrent in the initial seconds after light illumination and significantly increases the slope of the steady-state photocurrent versus the light intensity. The open-circuit voltage decay measurements further illustrate a longer electron lifetime when an amorphous TiOx interlayer is applied. Consequently, the photocurrent and photovoltage of the photovoltaic cell with a TiOx interlayer are greatly increased. This work emonstrates that the graphene/amorphous TiOx composite structure effectively inhibits charge recombination while enhancing charge transfer, providing a promising scaffold for quantum dots and dye-sensitized photovoltaic cells. 2011 Journal Article http://hdl.handle.net/20.500.11937/41348 American Chemical Society restricted
spellingShingle quantum dots
graphene
recombination
photochemistry
photovoltaic cells
Yang, H.
Guo, C.
Guai, G.
Song, Q.
Jiang, San Ping
Li, C.
Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title_full Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title_fullStr Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title_full_unstemmed Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title_short Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells
title_sort reduction of charge recombination by an amorphous titanium oxide interlayer in layered graphene/quantum dots photochemical cells
topic quantum dots
graphene
recombination
photochemistry
photovoltaic cells
url http://hdl.handle.net/20.500.11937/41348