Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene
© 2015 Taylor & Francis. The synthesis and characterisation of p-t-butylcalix[4]arene functionalised at the lower rim with four tetrazole moieties is reported. The macrocycle is found to be a poorer ionophore for lanthanoid cations than the bis-tetrazole-substituted analogue. Solution-phase phot...
| Main Authors: | , , , , , , , , |
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| Format: | Journal Article |
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2015
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| Online Access: | http://hdl.handle.net/20.500.11937/40409 |
| _version_ | 1848755863617011712 |
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| author | D'Alessio, Daniel Skelton, B. Lengkeek, N. Fraser, B. Krause-Heuer, A. Muzzioli, S. Stagni, S. Massi, Max Ogden, Mark |
| author_facet | D'Alessio, Daniel Skelton, B. Lengkeek, N. Fraser, B. Krause-Heuer, A. Muzzioli, S. Stagni, S. Massi, Max Ogden, Mark |
| author_sort | D'Alessio, Daniel |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2015 Taylor & Francis. The synthesis and characterisation of p-t-butylcalix[4]arene functionalised at the lower rim with four tetrazole moieties is reported. The macrocycle is found to be a poorer ionophore for lanthanoid cations than the bis-tetrazole-substituted analogue. Solution-phase photophysical studies strongly suggested that the cations interacted only weakly with the calixarene ligand. A mixed sodium/triethylammonium salt of the calixarene ligand was crystallised in the presence of lanthanoid cations and structurally characterised. Strong intramolecular interactions are hypothesised to be the cause of the observed behaviour. |
| first_indexed | 2025-11-14T09:03:04Z |
| format | Journal Article |
| id | curtin-20.500.11937-40409 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:03:04Z |
| publishDate | 2015 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-404092017-09-13T13:38:56Z Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene D'Alessio, Daniel Skelton, B. Lengkeek, N. Fraser, B. Krause-Heuer, A. Muzzioli, S. Stagni, S. Massi, Max Ogden, Mark © 2015 Taylor & Francis. The synthesis and characterisation of p-t-butylcalix[4]arene functionalised at the lower rim with four tetrazole moieties is reported. The macrocycle is found to be a poorer ionophore for lanthanoid cations than the bis-tetrazole-substituted analogue. Solution-phase photophysical studies strongly suggested that the cations interacted only weakly with the calixarene ligand. A mixed sodium/triethylammonium salt of the calixarene ligand was crystallised in the presence of lanthanoid cations and structurally characterised. Strong intramolecular interactions are hypothesised to be the cause of the observed behaviour. 2015 Journal Article http://hdl.handle.net/20.500.11937/40409 10.1080/10610278.2015.1075536 fulltext |
| spellingShingle | D'Alessio, Daniel Skelton, B. Lengkeek, N. Fraser, B. Krause-Heuer, A. Muzzioli, S. Stagni, S. Massi, Max Ogden, Mark Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title_full | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title_fullStr | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title_full_unstemmed | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title_short | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| title_sort | ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| url | http://hdl.handle.net/20.500.11937/40409 |