Thermodynamic estimation: Ionic materials
Thermodynamics establishes equilibrium relations among thermodynamic parameters (“properties”) and delineates the effects of variation of the thermodynamic functions (typically temperature and pressure) on those parameters. However, classical thermodynamics does not provide values for the necessary...
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| Format: | Journal Article |
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Elsevier Inc.
2013
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| Online Access: | http://hdl.handle.net/20.500.11937/40377 |
| _version_ | 1848755854625472512 |
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| author | Glasser, Leslie |
| author_facet | Glasser, Leslie |
| author_sort | Glasser, Leslie |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Thermodynamics establishes equilibrium relations among thermodynamic parameters (“properties”) and delineates the effects of variation of the thermodynamic functions (typically temperature and pressure) on those parameters. However, classical thermodynamics does not provide values for the necessary thermodynamic properties, which must be established by extra-thermodynamic means such as experiment, theoretical calculation, or empirical estimation.While many values may be found in the numerous collected tables in the literature, these are necessarily incomplete because either the experimental measurements have not been made or the materials may be hypothetical. The current paper presents a number of simple and relible estimation methods for thermodynamic properties, principally for ionic materials. The results may also be used as a check for obvious errors in published values.The estimation methods described are typically based on addition of properties of individual ions, or sums of properties of neutral ion groups (such as “double” salts, in the Simple Salt Approximation), or based upon correlations such as with formula unit volumes (Volume-Based Thermodynamics). |
| first_indexed | 2025-11-14T09:02:55Z |
| format | Journal Article |
| id | curtin-20.500.11937-40377 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:02:55Z |
| publishDate | 2013 |
| publisher | Elsevier Inc. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-403772019-02-19T04:26:13Z Thermodynamic estimation: Ionic materials Glasser, Leslie Properties correlatedwithvolume Additivityofproperties Thermodynamics Ionic materials Thermodynamics establishes equilibrium relations among thermodynamic parameters (“properties”) and delineates the effects of variation of the thermodynamic functions (typically temperature and pressure) on those parameters. However, classical thermodynamics does not provide values for the necessary thermodynamic properties, which must be established by extra-thermodynamic means such as experiment, theoretical calculation, or empirical estimation.While many values may be found in the numerous collected tables in the literature, these are necessarily incomplete because either the experimental measurements have not been made or the materials may be hypothetical. The current paper presents a number of simple and relible estimation methods for thermodynamic properties, principally for ionic materials. The results may also be used as a check for obvious errors in published values.The estimation methods described are typically based on addition of properties of individual ions, or sums of properties of neutral ion groups (such as “double” salts, in the Simple Salt Approximation), or based upon correlations such as with formula unit volumes (Volume-Based Thermodynamics). 2013 Journal Article http://hdl.handle.net/20.500.11937/40377 10.1016/j.jssc.2013.08.008 Elsevier Inc. fulltext |
| spellingShingle | Properties correlatedwithvolume Additivityofproperties Thermodynamics Ionic materials Glasser, Leslie Thermodynamic estimation: Ionic materials |
| title | Thermodynamic estimation: Ionic materials |
| title_full | Thermodynamic estimation: Ionic materials |
| title_fullStr | Thermodynamic estimation: Ionic materials |
| title_full_unstemmed | Thermodynamic estimation: Ionic materials |
| title_short | Thermodynamic estimation: Ionic materials |
| title_sort | thermodynamic estimation: ionic materials |
| topic | Properties correlatedwithvolume Additivityofproperties Thermodynamics Ionic materials |
| url | http://hdl.handle.net/20.500.11937/40377 |