Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes

Effects of sintering atmospheres on properties of SrCo0.4Fe0.5Zr0.1O3-d mixed-conducting membranes were in detail studied in terms of sintering behavior, electrical conductivity and oxygen permeability. The sintering atmospheres were 100% N2, 79% N2-21% O2, 60% N2-40% O2, 40% N2-60% O2, 20% N2-80% O...

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Main Authors: Chang, X., Zhang, C., Dong, X., Zhou, W., Jin, W., Shao, Zongping, Xu, N.
Format: Journal Article
Published: Elsevier BV 2008
Online Access:http://hdl.handle.net/20.500.11937/40124
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author Chang, X.
Zhang, C.
Dong, X.
Zhou, W.
Jin, W.
Shao, Zongping
Xu, N.
author_facet Chang, X.
Zhang, C.
Dong, X.
Zhou, W.
Jin, W.
Shao, Zongping
Xu, N.
author_sort Chang, X.
building Curtin Institutional Repository
collection Online Access
description Effects of sintering atmospheres on properties of SrCo0.4Fe0.5Zr0.1O3-d mixed-conducting membranes were in detail studied in terms of sintering behavior, electrical conductivity and oxygen permeability. The sintering atmospheres were 100% N2, 79% N2-21% O2, 60% N2-40% O2, 40% N2-60% O2, 20% N2-80% O2 and 100% O2 (in vol.%), and the prepared membranes were correspondingly denoted as S-0, S-21, S-40, S-60, S-80 and S-100, respectively. It was found that the properties of membranes were strongly dependent on the sintering atmosphere. As the oxygen partial pressure in the sintering atmosphere (PO2) increased, sintering ability, electrical conductivity and oxygen permeability decreased at first, which was in the order of S-0 > S-21 > S-40. However, as PO2 increased further, sintering ability, electrical conductivity and oxygen permeability increased gradually: S-40 < S-60 < S-80 < S-100. And the S-100 membrane had the best sintering ability, electrical conductivity and oxygen permeability in all membranes. © 2007 Elsevier B.V. All rights reserved.
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spelling curtin-20.500.11937-401242017-09-13T13:59:38Z Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes Chang, X. Zhang, C. Dong, X. Zhou, W. Jin, W. Shao, Zongping Xu, N. Effects of sintering atmospheres on properties of SrCo0.4Fe0.5Zr0.1O3-d mixed-conducting membranes were in detail studied in terms of sintering behavior, electrical conductivity and oxygen permeability. The sintering atmospheres were 100% N2, 79% N2-21% O2, 60% N2-40% O2, 40% N2-60% O2, 20% N2-80% O2 and 100% O2 (in vol.%), and the prepared membranes were correspondingly denoted as S-0, S-21, S-40, S-60, S-80 and S-100, respectively. It was found that the properties of membranes were strongly dependent on the sintering atmosphere. As the oxygen partial pressure in the sintering atmosphere (PO2) increased, sintering ability, electrical conductivity and oxygen permeability decreased at first, which was in the order of S-0 > S-21 > S-40. However, as PO2 increased further, sintering ability, electrical conductivity and oxygen permeability increased gradually: S-40 < S-60 < S-80 < S-100. And the S-100 membrane had the best sintering ability, electrical conductivity and oxygen permeability in all membranes. © 2007 Elsevier B.V. All rights reserved. 2008 Journal Article http://hdl.handle.net/20.500.11937/40124 10.1016/j.memsci.2007.09.040 Elsevier BV restricted
spellingShingle Chang, X.
Zhang, C.
Dong, X.
Zhou, W.
Jin, W.
Shao, Zongping
Xu, N.
Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title_full Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title_fullStr Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title_full_unstemmed Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title_short Effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
title_sort effects of sintering atmospheres on sintering behavior, electrical conductivity and oxygen permeability of mixed-conducting membranes
url http://hdl.handle.net/20.500.11937/40124