Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study

Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activa...

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Main Authors: Duan, X., Ao, Z., Sun, Hongqi, Zhou, L., Wang, G., Wang, S.
Format: Journal Article
Published: 2015
Online Access:http://purl.org/au-research/grants/arc/DP130101319
http://hdl.handle.net/20.500.11937/39647
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author Duan, X.
Ao, Z.
Sun, Hongqi
Zhou, L.
Wang, G.
Wang, S.
author_facet Duan, X.
Ao, Z.
Sun, Hongqi
Zhou, L.
Wang, G.
Wang, S.
author_sort Duan, X.
building Curtin Institutional Repository
collection Online Access
description Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T08:59:38Z
publishDate 2015
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spelling curtin-20.500.11937-396472022-10-06T06:33:18Z Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study Duan, X. Ao, Z. Sun, Hongqi Zhou, L. Wang, G. Wang, S. Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation. 2015 Journal Article http://hdl.handle.net/20.500.11937/39647 10.1039/c5cc05101k http://purl.org/au-research/grants/arc/DP130101319 fulltext
spellingShingle Duan, X.
Ao, Z.
Sun, Hongqi
Zhou, L.
Wang, G.
Wang, S.
Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title_full Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title_fullStr Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title_full_unstemmed Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title_short Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study
title_sort insights into n-doping in single-walled carbon nanotubes for enhanced activation of superoxides: a mechanistic study
url http://purl.org/au-research/grants/arc/DP130101319
http://hdl.handle.net/20.500.11937/39647