Resolving the scale dependency in laboratory and field weathering rates

Results from tracer studies in hydraulically-unsaturated column reactors containing mine rockdemonstrate that significant mass of pore water is relatively immobile. This water mass is retained within stagnant zones that do not contribute to advective transport of solutes in reactor effluent. Solutes...

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Bibliographic Details
Main Authors: Banwart, S., Zhang, C., Evans, Katy
Other Authors: R B Wanty
Format: Conference Paper
Published: Taylor and Francis Group 2004
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/3961
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author Banwart, S.
Zhang, C.
Evans, Katy
author2 R B Wanty
author_facet R B Wanty
Banwart, S.
Zhang, C.
Evans, Katy
author_sort Banwart, S.
building Curtin Institutional Repository
collection Online Access
description Results from tracer studies in hydraulically-unsaturated column reactors containing mine rockdemonstrate that significant mass of pore water is relatively immobile. This water mass is retained within stagnant zones that do not contribute to advective transport of solutes in reactor effluent. Solutes other than the inert tracer in the reactor effluent arise from chemical dissolution of minerals that compose the mine rock. Results demonstrate that the weathering rates of individual minerals can be quantified, if the effect of aqueous speciation, heterogeneous chemical equilibria and retention of solutes within stagnant zones are all considered. These results support the hypothesis that retention of solutes within stagnant zones at field sites contributes to the commonly observed discrepancy in weathering rates determined at laboratory and field scale.
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spelling curtin-20.500.11937-39612022-10-06T07:10:40Z Resolving the scale dependency in laboratory and field weathering rates Banwart, S. Zhang, C. Evans, Katy R B Wanty R R Seal II column reactors field weathering rates Results from tracer studies in hydraulically-unsaturated column reactors containing mine rockdemonstrate that significant mass of pore water is relatively immobile. This water mass is retained within stagnant zones that do not contribute to advective transport of solutes in reactor effluent. Solutes other than the inert tracer in the reactor effluent arise from chemical dissolution of minerals that compose the mine rock. Results demonstrate that the weathering rates of individual minerals can be quantified, if the effect of aqueous speciation, heterogeneous chemical equilibria and retention of solutes within stagnant zones are all considered. These results support the hypothesis that retention of solutes within stagnant zones at field sites contributes to the commonly observed discrepancy in weathering rates determined at laboratory and field scale. 2004 Conference Paper http://hdl.handle.net/20.500.11937/3961 Taylor and Francis Group fulltext
spellingShingle column reactors
field weathering rates
Banwart, S.
Zhang, C.
Evans, Katy
Resolving the scale dependency in laboratory and field weathering rates
title Resolving the scale dependency in laboratory and field weathering rates
title_full Resolving the scale dependency in laboratory and field weathering rates
title_fullStr Resolving the scale dependency in laboratory and field weathering rates
title_full_unstemmed Resolving the scale dependency in laboratory and field weathering rates
title_short Resolving the scale dependency in laboratory and field weathering rates
title_sort resolving the scale dependency in laboratory and field weathering rates
topic column reactors
field weathering rates
url http://hdl.handle.net/20.500.11937/3961