Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing

A new type of multifunctional plasmonic nanoparticles, cobalt-doped Fe2O3 at polydopamine-Au (Co-Fe2O3 at PDA-Au), is fabricated via coating PDA through self-polymerization onto Co-Fe2O3 and further loading gold nanoparticles by in situ reduction onto the surface of PDA shell. Benefiting from the un...

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Main Authors: Xiong, W., Zhao, Q., Li, Xin Yong, Wang, L.
Format: Journal Article
Published: 2016
Online Access:http://hdl.handle.net/20.500.11937/39467
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author Xiong, W.
Zhao, Q.
Li, Xin Yong
Wang, L.
author_facet Xiong, W.
Zhao, Q.
Li, Xin Yong
Wang, L.
author_sort Xiong, W.
building Curtin Institutional Repository
collection Online Access
description A new type of multifunctional plasmonic nanoparticles, cobalt-doped Fe2O3 at polydopamine-Au (Co-Fe2O3 at PDA-Au), is fabricated via coating PDA through self-polymerization onto Co-Fe2O3 and further loading gold nanoparticles by in situ reduction onto the surface of PDA shell. Benefiting from the universal adhesive ability of PDA and negative zeta potetntial of the composite, the Co-Fe2O3 at PDA-Au shows strong adsorptivity for cationic dyes. The presence of gold nanoparticle with the diameter of 15 nm in the Co-Fe2O3 at PDA-Au system promotes surface-enhanced Raman scattering (SERS) activity with an impressive detection limit of 1 × 10-6 m. Thanks to the synergistic effect of the light harvesting of PDA, the surface plasmon resonance of Au, and the electron conductibility of PDA and Au, the Co-Fe2O3 at PDA-Au exhibits an enhanced photocatalytic activity comparing with unmodified Co-Fe2O3. All the above-mentioned functions enable Co-Fe2O3 at PDA-Au to be a multifunctional material system for various applications toward environmental pollutants.
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spelling curtin-20.500.11937-394672017-09-13T14:24:48Z Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing Xiong, W. Zhao, Q. Li, Xin Yong Wang, L. A new type of multifunctional plasmonic nanoparticles, cobalt-doped Fe2O3 at polydopamine-Au (Co-Fe2O3 at PDA-Au), is fabricated via coating PDA through self-polymerization onto Co-Fe2O3 and further loading gold nanoparticles by in situ reduction onto the surface of PDA shell. Benefiting from the universal adhesive ability of PDA and negative zeta potetntial of the composite, the Co-Fe2O3 at PDA-Au shows strong adsorptivity for cationic dyes. The presence of gold nanoparticle with the diameter of 15 nm in the Co-Fe2O3 at PDA-Au system promotes surface-enhanced Raman scattering (SERS) activity with an impressive detection limit of 1 × 10-6 m. Thanks to the synergistic effect of the light harvesting of PDA, the surface plasmon resonance of Au, and the electron conductibility of PDA and Au, the Co-Fe2O3 at PDA-Au exhibits an enhanced photocatalytic activity comparing with unmodified Co-Fe2O3. All the above-mentioned functions enable Co-Fe2O3 at PDA-Au to be a multifunctional material system for various applications toward environmental pollutants. 2016 Journal Article http://hdl.handle.net/20.500.11937/39467 10.1002/ppsc.201600085 restricted
spellingShingle Xiong, W.
Zhao, Q.
Li, Xin Yong
Wang, L.
Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title_full Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title_fullStr Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title_full_unstemmed Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title_short Multifunctional Plasmonic Co-Doped Fe2O3@polydopamine-Au for Adsorption, Photocatalysis, and SERS-based Sensing
title_sort multifunctional plasmonic co-doped fe2o3@polydopamine-au for adsorption, photocatalysis, and sers-based sensing
url http://hdl.handle.net/20.500.11937/39467