Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion?
In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5′-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammoni...
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| Format: | Journal Article |
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John Wiley & Sons Ltd
2014
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| Online Access: | http://hdl.handle.net/20.500.11937/38828 |
| _version_ | 1848755425880571904 |
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| author | Glasser, Leslie Jenkins, H.D. Klapotke, T. |
| author_facet | Glasser, Leslie Jenkins, H.D. Klapotke, T. |
| author_sort | Glasser, Leslie |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5′-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammonium 5,5′-(tetrazolate-1N-oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts. |
| first_indexed | 2025-11-14T08:56:06Z |
| format | Journal Article |
| id | curtin-20.500.11937-38828 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:56:06Z |
| publishDate | 2014 |
| publisher | John Wiley & Sons Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-388282019-02-19T05:35:13Z Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? Glasser, Leslie Jenkins, H.D. Klapotke, T. Lattice enthalpy Volume-based thermodynamics (VBT) Tetrazole Explosives TKX-50 In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5′-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammonium 5,5′-(tetrazolate-1N-oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts. 2014 Journal Article http://hdl.handle.net/20.500.11937/38828 10.1002/zaac.201400007 John Wiley & Sons Ltd fulltext |
| spellingShingle | Lattice enthalpy Volume-based thermodynamics (VBT) Tetrazole Explosives TKX-50 Glasser, Leslie Jenkins, H.D. Klapotke, T. Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title | Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title_full | Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title_fullStr | Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title_full_unstemmed | Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title_short | Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5'-(Tetrazolate-1N-oxide) Dianion? |
| title_sort | is the volume-based thermodynamics (vbt) approach valid for the estimation of the lattice enthalpy of salts containing the 5,5'-(tetrazolate-1n-oxide) dianion? |
| topic | Lattice enthalpy Volume-based thermodynamics (VBT) Tetrazole Explosives TKX-50 |
| url | http://hdl.handle.net/20.500.11937/38828 |