Rechargeable Aqueous Microdroplet

Directional and controllable transportation of microdroplets is critical for emerging micro- and nanotechnology, in which the conventional mechanical energy generation is not applicable. This Letter shows that an aqueous microdroplet can be charged for controlled motion in electrostatic potential, w...

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Main Author: Phan, Chi
Format: Journal Article
Published: American Chemical Society 2014
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/38347
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author Phan, Chi
author_facet Phan, Chi
author_sort Phan, Chi
building Curtin Institutional Repository
collection Online Access
description Directional and controllable transportation of microdroplets is critical for emerging micro- and nanotechnology, in which the conventional mechanical energy generation is not applicable. This Letter shows that an aqueous microdroplet can be charged for controlled motion in electrostatic potential, which was created by differentiating pH, between two oil/water interfaces. The directional motion of the droplet, <100 micro-meters in diameter, was obtained with a constant velocity of ~1 mm/s. The force analysis showed that the droplet surface was charged and recharged oppositely byion transfer through interfacial layers, without significant mass transfer. The charging and recharging cycles were recorded continuously with a single droplet over 100 times. The energy for motion was generated from pH neutralization, which is the simplest aqueous reaction. This is the first time that the phenomenon is reported. The phenomenon can be employed as an efficient and robust method to convert chemical to mechanical energy for miniaturized devices and microprocesses.
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spelling curtin-20.500.11937-383472017-09-13T16:01:26Z Rechargeable Aqueous Microdroplet Phan, Chi pH neutralization liquid/liquid interface ionic transfer surface potential microtransportation Directional and controllable transportation of microdroplets is critical for emerging micro- and nanotechnology, in which the conventional mechanical energy generation is not applicable. This Letter shows that an aqueous microdroplet can be charged for controlled motion in electrostatic potential, which was created by differentiating pH, between two oil/water interfaces. The directional motion of the droplet, <100 micro-meters in diameter, was obtained with a constant velocity of ~1 mm/s. The force analysis showed that the droplet surface was charged and recharged oppositely byion transfer through interfacial layers, without significant mass transfer. The charging and recharging cycles were recorded continuously with a single droplet over 100 times. The energy for motion was generated from pH neutralization, which is the simplest aqueous reaction. This is the first time that the phenomenon is reported. The phenomenon can be employed as an efficient and robust method to convert chemical to mechanical energy for miniaturized devices and microprocesses. 2014 Journal Article http://hdl.handle.net/20.500.11937/38347 10.1021/jz500556n American Chemical Society fulltext
spellingShingle pH neutralization
liquid/liquid interface
ionic transfer
surface potential
microtransportation
Phan, Chi
Rechargeable Aqueous Microdroplet
title Rechargeable Aqueous Microdroplet
title_full Rechargeable Aqueous Microdroplet
title_fullStr Rechargeable Aqueous Microdroplet
title_full_unstemmed Rechargeable Aqueous Microdroplet
title_short Rechargeable Aqueous Microdroplet
title_sort rechargeable aqueous microdroplet
topic pH neutralization
liquid/liquid interface
ionic transfer
surface potential
microtransportation
url http://hdl.handle.net/20.500.11937/38347