Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach

In modern materials science, there is a plethora of characterization techniques of materials that can provide valuable insights into the fundamental chemical physics of solid-state devices such as chalcogenide glass ion-selective electrodes (ISEs). In this paper, electrochemical impedance spectrosco...

Full description

Bibliographic Details
Main Authors: De Marco, Roland, Jiang, Zhong-Tao, Becker, Thomas, Clarke, Graeme, Murgatroyd, G., Prince, K.
Format: Journal Article
Published: Wiley-VCH Verlag GmbH 2006
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/38274
_version_ 1848755275936301056
author De Marco, Roland
Jiang, Zhong-Tao
Becker, Thomas
Clarke, Graeme
Murgatroyd, G.
Prince, K.
author_facet De Marco, Roland
Jiang, Zhong-Tao
Becker, Thomas
Clarke, Graeme
Murgatroyd, G.
Prince, K.
author_sort De Marco, Roland
building Curtin Institutional Repository
collection Online Access
description In modern materials science, there is a plethora of characterization techniques of materials that can provide valuable insights into the fundamental chemical physics of solid-state devices such as chalcogenide glass ion-selective electrodes (ISEs). In this paper, electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectrometry (XPS) and secondary ion mass spectrometry (SIMS) have been used in the elucidation of the mechanistic chemistry of the cadmium chalcogenide glass ISE. Furthermore, in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD), in situ EIS/SR-GIXRD, along with small angle neutron scattering (SANS), can be used to unravel the complex relationship between the nanostructure, bulk electrical conductivity and concomitant electrochemical reactivity of an iron chalcogenide glass ISE. Significantly, exciting preliminary modified atomic force microscopy (AFM) data utilizing AFM cantilevers with attached microparticles of the copper sensing material jalpaite demonstrate the tremendous potential of selective force ISE-AFM in the imaging of important molecular structures such as the copper ion channels of cell membranes in fish gills and/or phytoplankton
first_indexed 2025-11-14T08:53:43Z
format Journal Article
id curtin-20.500.11937-38274
institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T08:53:43Z
publishDate 2006
publisher Wiley-VCH Verlag GmbH
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-382742019-02-19T05:35:12Z Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach De Marco, Roland Jiang, Zhong-Tao Becker, Thomas Clarke, Graeme Murgatroyd, G. Prince, K. Surface analysis Ion-selective electrode Materials science Chalcogenide glasses Atomic force microscopy In modern materials science, there is a plethora of characterization techniques of materials that can provide valuable insights into the fundamental chemical physics of solid-state devices such as chalcogenide glass ion-selective electrodes (ISEs). In this paper, electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectrometry (XPS) and secondary ion mass spectrometry (SIMS) have been used in the elucidation of the mechanistic chemistry of the cadmium chalcogenide glass ISE. Furthermore, in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD), in situ EIS/SR-GIXRD, along with small angle neutron scattering (SANS), can be used to unravel the complex relationship between the nanostructure, bulk electrical conductivity and concomitant electrochemical reactivity of an iron chalcogenide glass ISE. Significantly, exciting preliminary modified atomic force microscopy (AFM) data utilizing AFM cantilevers with attached microparticles of the copper sensing material jalpaite demonstrate the tremendous potential of selective force ISE-AFM in the imaging of important molecular structures such as the copper ion channels of cell membranes in fish gills and/or phytoplankton 2006 Journal Article http://hdl.handle.net/20.500.11937/38274 10.1002/elan.200503524 Wiley-VCH Verlag GmbH restricted
spellingShingle Surface analysis
Ion-selective electrode
Materials science
Chalcogenide glasses
Atomic force microscopy
De Marco, Roland
Jiang, Zhong-Tao
Becker, Thomas
Clarke, Graeme
Murgatroyd, G.
Prince, K.
Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title_full Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title_fullStr Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title_full_unstemmed Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title_short Response Mechanisms and New Approaches with Solid-State Ion-Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach
title_sort response mechanisms and new approaches with solid-state ion-selective electrodes: a powerful multitechnique materials characterization approach
topic Surface analysis
Ion-selective electrode
Materials science
Chalcogenide glasses
Atomic force microscopy
url http://hdl.handle.net/20.500.11937/38274