Bottom-up nanofabrication of materials for organic electronics

Self-organising functional systems and devices are the ultimate aim of bottom-up fabrication. Here, we show how spontaneous organisation can be exploited for patterning a variety of materials, relevant to organic electronics, into arrays of lines or dots by means of a stamp-assisted deposition metho...

Full description

Bibliographic Details
Main Authors: Facchini, M., Cavallini, M., Massi, Massimiliano, Biscarini, F.
Format: Journal Article
Published: ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND 2004
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/3808
_version_ 1848744332839878656
author Facchini, M.
Cavallini, M.
Massi, Massimiliano
Biscarini, F.
author_facet Facchini, M.
Cavallini, M.
Massi, Massimiliano
Biscarini, F.
author_sort Facchini, M.
building Curtin Institutional Repository
collection Online Access
description Self-organising functional systems and devices are the ultimate aim of bottom-up fabrication. Here, we show how spontaneous organisation can be exploited for patterning a variety of materials, relevant to organic electronics, into arrays of lines or dots by means of a stamp-assisted deposition method, termed lithographically controlled wetting (LCW). LCW is a versatile bottom-up method, able to exploit the spontaneous properties of materials; a stamp is gently placed on a solution layer cast on a substrate. Capillary forces pin the layer to the stamp protrusions, and the hydrodynamic flow during solvent evaporation moves the solution under the protrusions. As the critical concentration is achieved, the solute precipitates only in the regions where the solution is confined by the menisci, and the pattern exhibits the motif of the stamp. By changing concentration or stamp-substrate distance, it is possible to downscale the feature size down to sub-100 nm length scale. Spatially organised nanodots or crystallites can be fabricated by exploiting dewetting, ripening and crystallization.
first_indexed 2025-11-14T05:59:47Z
format Journal Article
id curtin-20.500.11937-3808
institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T05:59:47Z
publishDate 2004
publisher ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-38082017-09-13T16:09:32Z Bottom-up nanofabrication of materials for organic electronics Facchini, M. Cavallini, M. Massi, Massimiliano Biscarini, F. SCALE lithographically controlled wetting - SINGLE-MOLECULE MAGNETS bottom-up nanofabrication organic electronics PATTERNS Self-organising functional systems and devices are the ultimate aim of bottom-up fabrication. Here, we show how spontaneous organisation can be exploited for patterning a variety of materials, relevant to organic electronics, into arrays of lines or dots by means of a stamp-assisted deposition method, termed lithographically controlled wetting (LCW). LCW is a versatile bottom-up method, able to exploit the spontaneous properties of materials; a stamp is gently placed on a solution layer cast on a substrate. Capillary forces pin the layer to the stamp protrusions, and the hydrodynamic flow during solvent evaporation moves the solution under the protrusions. As the critical concentration is achieved, the solute precipitates only in the regions where the solution is confined by the menisci, and the pattern exhibits the motif of the stamp. By changing concentration or stamp-substrate distance, it is possible to downscale the feature size down to sub-100 nm length scale. Spatially organised nanodots or crystallites can be fabricated by exploiting dewetting, ripening and crystallization. 2004 Journal Article http://hdl.handle.net/20.500.11937/3808 10.1016/j.synthmet.2004.08.006 ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND restricted
spellingShingle SCALE
lithographically controlled wetting - SINGLE-MOLECULE MAGNETS
bottom-up nanofabrication
organic electronics
PATTERNS
Facchini, M.
Cavallini, M.
Massi, Massimiliano
Biscarini, F.
Bottom-up nanofabrication of materials for organic electronics
title Bottom-up nanofabrication of materials for organic electronics
title_full Bottom-up nanofabrication of materials for organic electronics
title_fullStr Bottom-up nanofabrication of materials for organic electronics
title_full_unstemmed Bottom-up nanofabrication of materials for organic electronics
title_short Bottom-up nanofabrication of materials for organic electronics
title_sort bottom-up nanofabrication of materials for organic electronics
topic SCALE
lithographically controlled wetting - SINGLE-MOLECULE MAGNETS
bottom-up nanofabrication
organic electronics
PATTERNS
url http://hdl.handle.net/20.500.11937/3808