Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide

The inhibition performance of thiobenzamide (TB) against the under deposit corrosion of carbon steel in CO2-saturated, chloride-containing environment has been investigated. TB concentrations were varied from 10 - 200 ppm and temperature from 30 degrees centigrade to 60 degrees centigrade were teste...

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Main Authors: Pandarinathan, Vedapriya, Lepkova, Katerina, Bailey, Stuart, Gubner, Rolf
Format: Journal Article
Published: The Electrochemical Society, Inc 2013
Online Access:http://hdl.handle.net/20.500.11937/38006
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author Pandarinathan, Vedapriya
Lepkova, Katerina
Bailey, Stuart
Gubner, Rolf
author_facet Pandarinathan, Vedapriya
Lepkova, Katerina
Bailey, Stuart
Gubner, Rolf
author_sort Pandarinathan, Vedapriya
building Curtin Institutional Repository
collection Online Access
description The inhibition performance of thiobenzamide (TB) against the under deposit corrosion of carbon steel in CO2-saturated, chloride-containing environment has been investigated. TB concentrations were varied from 10 - 200 ppm and temperature from 30 degrees centigrade to 60 degrees centigrade were tested. TB effectively inhibits corrosion at carbon steel surfaces with and without sand deposits, reducing the general corrosion rates below 0.1 mm y-1 in all cases studied. Electrochemical tests results sugest that inhibition occurs via adsorption at the steel surface through the S atom of the TB molecule. Potentiodynamic polarization measurements show that the inhibition mechanism differs at surfaces with and without sand deposits with temperature change over the range of 30 degrees centigrade to 60 degrees centigrade. Surface analysis of the corroded steels showed that general corrosion takes place at surfaces without sand deposits, whereas localized corrosion proceeds at the surfaces underneath a sand deposit, both in the presencea and absence of thiobenzamide.
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institution Curtin University Malaysia
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last_indexed 2025-11-14T08:52:34Z
publishDate 2013
publisher The Electrochemical Society, Inc
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spelling curtin-20.500.11937-380062017-09-13T14:10:55Z Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide Pandarinathan, Vedapriya Lepkova, Katerina Bailey, Stuart Gubner, Rolf The inhibition performance of thiobenzamide (TB) against the under deposit corrosion of carbon steel in CO2-saturated, chloride-containing environment has been investigated. TB concentrations were varied from 10 - 200 ppm and temperature from 30 degrees centigrade to 60 degrees centigrade were tested. TB effectively inhibits corrosion at carbon steel surfaces with and without sand deposits, reducing the general corrosion rates below 0.1 mm y-1 in all cases studied. Electrochemical tests results sugest that inhibition occurs via adsorption at the steel surface through the S atom of the TB molecule. Potentiodynamic polarization measurements show that the inhibition mechanism differs at surfaces with and without sand deposits with temperature change over the range of 30 degrees centigrade to 60 degrees centigrade. Surface analysis of the corroded steels showed that general corrosion takes place at surfaces without sand deposits, whereas localized corrosion proceeds at the surfaces underneath a sand deposit, both in the presencea and absence of thiobenzamide. 2013 Journal Article http://hdl.handle.net/20.500.11937/38006 10.1149/2.078309jes The Electrochemical Society, Inc restricted
spellingShingle Pandarinathan, Vedapriya
Lepkova, Katerina
Bailey, Stuart
Gubner, Rolf
Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title_full Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title_fullStr Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title_full_unstemmed Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title_short Inhibition of Under-Deposit Corrosion of Carbon Steel by Thiobenzamide
title_sort inhibition of under-deposit corrosion of carbon steel by thiobenzamide
url http://hdl.handle.net/20.500.11937/38006