Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag

In this work, hollow “spindle-like” α-Fe2O3 nanoparticles were synthesized by a hydrothermal route. The Ag/α-Fe2O3 catalyst was prepared based on the spindle-shaped α-Fe2O3 with CTAB as the surfactant, which showed excellent photoelectric property and photocatalytic activity. The structural properti...

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Main Authors: Li, H., Zhao, Q., Li, Xin Yong, Shi, Y., Zhu, Z., Tade, Moses, Liu, Shaomin
Format: Journal Article
Published: PERGAMON-ELSEVIER SCIENCE LTD 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/37919
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author Li, H.
Zhao, Q.
Li, Xin Yong
Shi, Y.
Zhu, Z.
Tade, Moses
Liu, Shaomin
author_facet Li, H.
Zhao, Q.
Li, Xin Yong
Shi, Y.
Zhu, Z.
Tade, Moses
Liu, Shaomin
author_sort Li, H.
building Curtin Institutional Repository
collection Online Access
description In this work, hollow “spindle-like” α-Fe2O3 nanoparticles were synthesized by a hydrothermal route. The Ag/α-Fe2O3 catalyst was prepared based on the spindle-shaped α-Fe2O3 with CTAB as the surfactant, which showed excellent photoelectric property and photocatalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction, scanning electronic microscopy, transmission electronic microscopy, energy-dispersive X-ray spectra, and UV–Vis diffuse reflectance spectroscopy techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage measurement. The photocatalytic performances of the Ag/α-Fe2O3 and α-Fe2O3 samples were comparatively studied in the degradation of toluene under xenon lamp irradiation by in situ FTIR spectroscopy. Benzaldehyde and benzoic acid species could be observed on the α-Fe2O3 surface rather than Ag/α-Fe2O3 surface. The results indicate that the Ag/α-Fe2O3 sample exhibited higher photocatalytic efficiency.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T08:52:11Z
publishDate 2012
publisher PERGAMON-ELSEVIER SCIENCE LTD
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-379192017-09-13T14:13:45Z Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag Li, H. Zhao, Q. Li, Xin Yong Shi, Y. Zhu, Z. Tade, Moses Liu, Shaomin D. Catalytic properties A. Composites C. Electron microscopy B. Chemical synthesis C. Infrared spectroscopy In this work, hollow “spindle-like” α-Fe2O3 nanoparticles were synthesized by a hydrothermal route. The Ag/α-Fe2O3 catalyst was prepared based on the spindle-shaped α-Fe2O3 with CTAB as the surfactant, which showed excellent photoelectric property and photocatalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction, scanning electronic microscopy, transmission electronic microscopy, energy-dispersive X-ray spectra, and UV–Vis diffuse reflectance spectroscopy techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage measurement. The photocatalytic performances of the Ag/α-Fe2O3 and α-Fe2O3 samples were comparatively studied in the degradation of toluene under xenon lamp irradiation by in situ FTIR spectroscopy. Benzaldehyde and benzoic acid species could be observed on the α-Fe2O3 surface rather than Ag/α-Fe2O3 surface. The results indicate that the Ag/α-Fe2O3 sample exhibited higher photocatalytic efficiency. 2012 Journal Article http://hdl.handle.net/20.500.11937/37919 10.1016/j.materresbull.2012.02.039 PERGAMON-ELSEVIER SCIENCE LTD restricted
spellingShingle D. Catalytic properties
A. Composites
C. Electron microscopy
B. Chemical synthesis
C. Infrared spectroscopy
Li, H.
Zhao, Q.
Li, Xin Yong
Shi, Y.
Zhu, Z.
Tade, Moses
Liu, Shaomin
Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title_full Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title_fullStr Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title_full_unstemmed Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title_short Photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-Fe2O3 loaded with Ag
title_sort photocatalytic degradation of gaseous toluene over hollow ‘‘spindle-like’’ a-fe2o3 loaded with ag
topic D. Catalytic properties
A. Composites
C. Electron microscopy
B. Chemical synthesis
C. Infrared spectroscopy
url http://hdl.handle.net/20.500.11937/37919