Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes

The clear coats from a collection of automotive paint samples of 139 vehicles, covering a range of Australian and international vehicle manufacturers and sold in Western Australia, were characterised using FT-Raman spectroscopy. Principal component analysis (PCA) revealed 19 distinct classes that we...

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Main Authors: Maric, M., van Bronswijk, Wilhelm, Pitts, K., Lewis, Simon
Format: Journal Article
Published: John Wiley & Sons Ltd 2016
Online Access:http://hdl.handle.net/20.500.11937/37089
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author Maric, M.
van Bronswijk, Wilhelm
Pitts, K.
Lewis, Simon
author_facet Maric, M.
van Bronswijk, Wilhelm
Pitts, K.
Lewis, Simon
author_sort Maric, M.
building Curtin Institutional Repository
collection Online Access
description The clear coats from a collection of automotive paint samples of 139 vehicles, covering a range of Australian and international vehicle manufacturers and sold in Western Australia, were characterised using FT-Raman spectroscopy. Principal component analysis (PCA) revealed 19 distinct classes that were associated with the vehicles' manufacturer and model, and in the case of Australian manufacturers, the years of manufacture. Linear discriminant analysis based on the PCA groupings gave excellent discrimination between the groups with 96.9% of the calibration set and 97.6% of the validation set being correctly classified. Although the sample set comprised only vehicles available in Australia, the methodology used is universal and hence applicable in any jurisdiction that is willing and able to generate a statistically significant data set and maintain and update it as new vehicles appear on the market. A FT-Raman spectroscopy-based database would rapidly provide information regarding vehicle origin and manufacture and hence generate investigative leads for questioned paint samples found at incident sites.
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institution Curtin University Malaysia
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last_indexed 2025-11-14T08:48:34Z
publishDate 2016
publisher John Wiley & Sons Ltd
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spelling curtin-20.500.11937-370892017-09-13T14:01:06Z Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes Maric, M. van Bronswijk, Wilhelm Pitts, K. Lewis, Simon The clear coats from a collection of automotive paint samples of 139 vehicles, covering a range of Australian and international vehicle manufacturers and sold in Western Australia, were characterised using FT-Raman spectroscopy. Principal component analysis (PCA) revealed 19 distinct classes that were associated with the vehicles' manufacturer and model, and in the case of Australian manufacturers, the years of manufacture. Linear discriminant analysis based on the PCA groupings gave excellent discrimination between the groups with 96.9% of the calibration set and 97.6% of the validation set being correctly classified. Although the sample set comprised only vehicles available in Australia, the methodology used is universal and hence applicable in any jurisdiction that is willing and able to generate a statistically significant data set and maintain and update it as new vehicles appear on the market. A FT-Raman spectroscopy-based database would rapidly provide information regarding vehicle origin and manufacture and hence generate investigative leads for questioned paint samples found at incident sites. 2016 Journal Article http://hdl.handle.net/20.500.11937/37089 10.1002/jrs.4925 John Wiley & Sons Ltd restricted
spellingShingle Maric, M.
van Bronswijk, Wilhelm
Pitts, K.
Lewis, Simon
Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title_full Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title_fullStr Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title_full_unstemmed Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title_short Characterisation and classification of automotive clear coats with Raman spectroscopy and chemometrics for forensic purposes
title_sort characterisation and classification of automotive clear coats with raman spectroscopy and chemometrics for forensic purposes
url http://hdl.handle.net/20.500.11937/37089