Improvement of the Derjaguin−Broekhoff−de Boer Theory for Capillary Condensation/Evaporation of Nitrogen in Mesoporous Systems and Its Implications for Pore Size Analysis of MCM-41 Silicas and Related Materials

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Improvement of the Derjaguin−Broekhoff−de Boer Theory for Capillary Condensation/Evaporation of Nitrogen in Mesoporous Systems and Its Implications for Pore Size Analysis of MCM-41 Silicas and Related Materials

In this work, we propose an improvement of the classical Derjaguin−Broekhoff−de Boer (DBdB) theory for capillary condensation/evaporation in mesoporous systems. The primary idea of this improvement is to employ the Gibbs−Tolman−Koenig−Buff equation to predict the surface tension changes in mesopores...

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Bibliographic Details
Main Authors:	Kowalczyk, Piotr, Jaroniec, M., Terzyk, A., Kaneko, K., Do, D.
Format:	Journal Article
Published:	American Chemical Society 2005
Online Access:	http://hdl.handle.net/20.500.11937/36948

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