Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes

A multiwalled carbon nanotube (MWCNT) was used as an adsorbent for removal of a cationic dye(methylene blue, MB) and acid dye (acid red 183, AR183) from aqueous solution in single and binarydye systems. Characterization of the MWCNT and MWCNT-dye systems were performed using several techniques such...

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Main Authors: Wang, Shaobin, Ng., C., Wang, Wentai, Li, Qin, Hao, Z.
Format: Journal Article
Published: Elsevier BV 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/35844
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author Wang, Shaobin
Ng., C.
Wang, Wentai
Li, Qin
Hao, Z.
author_facet Wang, Shaobin
Ng., C.
Wang, Wentai
Li, Qin
Hao, Z.
author_sort Wang, Shaobin
building Curtin Institutional Repository
collection Online Access
description A multiwalled carbon nanotube (MWCNT) was used as an adsorbent for removal of a cationic dye(methylene blue, MB) and acid dye (acid red 183, AR183) from aqueous solution in single and binarydye systems. Characterization of the MWCNT and MWCNT-dye systems were performed using several techniques such as Fourier transform infrared spectroscopy (FTIR), thermogravimetric–differential thermal analysis (TG–DTA), zeta potential and elemental analysis. Adsorption tests showed that the MWCNT presented higher adsorption of MB than AR183 in single and binary dye systems, revealing that p–p stacking is the main driving force responsible for the dye–MWCNT interaction. In single dye systems, the MWCNT presented the maximum adsorption capacities of MB and AR183 at 59.7 and 45.2 mg/g, respectively. In a binary dye system, a synergistic effect due to electronic attraction between MB and AR183 was found at low AR183 concentration (10 mg/L), which promotes the adsorption of both dyes on the MWCNT. However, MB adsorption could be reduced at higher AR183 concentration (>20 mg/L) due to a strong electrostatic attraction between MWCNT-AR183.
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institution Curtin University Malaysia
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publishDate 2012
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spelling curtin-20.500.11937-358442018-03-29T09:09:00Z Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes Wang, Shaobin Ng., C. Wang, Wentai Li, Qin Hao, Z. Acid red 183 Multi-wall carbon nanotube Methylene blue Dye adsorption A multiwalled carbon nanotube (MWCNT) was used as an adsorbent for removal of a cationic dye(methylene blue, MB) and acid dye (acid red 183, AR183) from aqueous solution in single and binarydye systems. Characterization of the MWCNT and MWCNT-dye systems were performed using several techniques such as Fourier transform infrared spectroscopy (FTIR), thermogravimetric–differential thermal analysis (TG–DTA), zeta potential and elemental analysis. Adsorption tests showed that the MWCNT presented higher adsorption of MB than AR183 in single and binary dye systems, revealing that p–p stacking is the main driving force responsible for the dye–MWCNT interaction. In single dye systems, the MWCNT presented the maximum adsorption capacities of MB and AR183 at 59.7 and 45.2 mg/g, respectively. In a binary dye system, a synergistic effect due to electronic attraction between MB and AR183 was found at low AR183 concentration (10 mg/L), which promotes the adsorption of both dyes on the MWCNT. However, MB adsorption could be reduced at higher AR183 concentration (>20 mg/L) due to a strong electrostatic attraction between MWCNT-AR183. 2012 Journal Article http://hdl.handle.net/20.500.11937/35844 10.1016/j.cej.2012.05.008 Elsevier BV restricted
spellingShingle Acid red 183
Multi-wall carbon nanotube
Methylene blue
Dye adsorption
Wang, Shaobin
Ng., C.
Wang, Wentai
Li, Qin
Hao, Z.
Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title_full Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title_fullStr Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title_full_unstemmed Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title_short Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
title_sort synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes
topic Acid red 183
Multi-wall carbon nanotube
Methylene blue
Dye adsorption
url http://hdl.handle.net/20.500.11937/35844